Mechanism of C-O Activation in Dimethoxyethane Cationic Iron Complexes

Sophie Le Caer; Michel Heninger; Pascal Pernot

首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Mechanism of C-O Activation in Dimethoxyethane Cationic Iron Complexes

【24h】

Mechanism of C-O Activation in Dimethoxyethane Cationic Iron Complexes

机译：二甲氧基乙烷阳离子铁配合物中C-O活化的机理

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The fragmentation mechanism of iron complexes bearing a bidentate ligand,dimethoxyethane(CH_3OCH_2-CH_2OCH_3,labeled as DXE)has been investigated by means of FT-ICR mass spectrometry(ion-molecule reactions)and infrared multiphoton dissociation spectroscopy.Two possible reaction mechanisms were envisioned for the Fe(DXE)~+ + DXE reaction,leading to the formation of the Fe(CH_2O)(DXE)~+ ion.The two mechanisms differ in the nature of the neutral molecules formed:CH_3OC_2H_5 or CH_2 ident to CH_2 + CH_3OH.The combination of ion-molecule reactions,thermochemistry considerations,and IRMPD spectra leads us to suggest that the mechanism involves successive elimination of the neutrals CH_2=CH_2 and CH_3OH,the first step of the mechanism being the insertion of the iron atom in the O-C_(central)bond.

机译：通过FT-ICR质谱（离子-分子反应）和红外多光子离解光谱法研究了带有双齿配体二甲氧基乙烷（CH_3OCH_2-CH_2OCH_3，标记为DXE）的铁配合物的断裂机理。设想了两种可能的反应机理Fe（DXE）〜+ DXE反应，导致形成Fe（CH_2O）（DXE）〜+离子。两种机理在所形成的中性分子的性质上有所不同：CH_3OC_2H_5或与CH_2 + CH_3OH相同的CH_2离子-分子反应，热化学考虑和IRMPD光谱的结合使我们认为该机理涉及连续消除中性基团CH_2 = CH_2和CH_3OH，机理的第一步是将铁原子插入O -C_（中央）键。

著录项

来源
《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2006年第10期|共11页
作者
Sophie Le Caer; Michel Heninger; Pascal Pernot;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Mechanism of C-O activation in dimethoxyethane cationic iron complexes [J] . Le Caer S, Heninger M, Pernot P, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2006,第31期

机译：二甲氧基乙烷阳离子铁配合物中C-O活化的机理
2. Mechanism of C-O Activation in Dimethoxyethane Cationic Iron Complexes [J] . Sophie Le Caer, Michel Heninger, Pascal Pernot The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2006,第10期

机译：二甲氧基乙烷阳离子铁配合物中C-O活化的机理
3. Mechanism of C-O Activation in Dimethoxyethane Cationic Iron Complexes [J] . Sophie Le Caer, Michel Heninger, Pascal Pernot The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2006,第10期

机译：二甲氧基乙烷阳离子铁配合物中C-O活化的机理
4. Activation of Polarized Single Bonds by Complexes Having an Iron-Silicon-Phosphorus Linkage [C] . Kveone A Jung, Masaaki Okazaki, Hiromi Tobita Symposium on Organometallic Chemistry . 2003

机译：通过具有铁 - 硅 - 磷键的复合物激活偏振单键
5. Electronic Structure Investigation of Low Valent Novel Iron Complexes: Mechanisms of C—H Activation and Magnetic Studies [D] . Lutz, Sean A. 2020

机译：低价小型铁复合物的电子结构研究：C-H激活和磁性研究的机制
6. Cationic Lipid–Nucleic Acid Complexes for Gene Delivery and Silencing: Pathways and Mechanisms for Plasmid DNA and siRNA [O] . Kai K. Ewert, Alexandra Zidovska, Ayesha Ahmad, -1

机译：基因递送和沉默的阳离子脂质 - 核酸复合物：质粒DNA和siRNA的途径和机制
7. Evidence for an Equilibrium between Neutral and Cationic Arylpalladium(II) Complexes in DMF. Mechanism of the Reduction of Cationic Arylpalladium(II) Complexes. [O] . Christian Amatore, Emmanuelle Carré, Anny Jutand, 1998

机译：DMF中中性和阳离子芳基钯（II）复合物之间平衡的证据。减少阳离子芳基钯（II）配合物的机理。
8. Mechanism of the Initiation of the Cationic Polymerization of Styrenes by Silanes and Activated Covalent Esters [R] . Matyjaszewski, K. 1989

机译：硅烷和活化共价酯引发苯乙烯阳离子聚合的机理

Mechanism of C-O Activation in Dimethoxyethane Cationic Iron Complexes

摘要

著录项

相似文献

相关主题

期刊订阅