Temperature and pressure dependence of the rate constants of the reaction of NO3 radical with CH3SCH3

Nakano Y; Ishiwata T; Aloisio S; Kawasaki M

首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Temperature and pressure dependence of the rate constants of the reaction of NO3 radical with CH3SCH3

【24h】

Temperature and pressure dependence of the rate constants of the reaction of NO3 radical with CH3SCH3

机译：NO3自由基与CH3SCH3反应速率常数的温度和压力依赖性

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The reaction of nitrate radical with dimethyl sulfide was studied with cavity ring-down spectroscopy in 20200 Torr of N-2 diluent in the temperature range of 283 - 318 K. The rate constant for this reaction, k(1), is found to be temperature dependent and pressure independent: k(1) = 4.5(-2.8)(+4.0) x 10(-13) exp[(310 +/- 220)/T]cm(3) molecule(-1) s(-1). The uncertainties are two standard deviations from regression analyses. The present rate constants are in good agreement with those reported by Daykin and Wine (Int. J. Chem. Kinet. 1990, 22, 1083) and may be used in the atmospheric model calculation. Theoretical calculations were carried out to verify the existence of an intermediate complex.

机译：在20200托N-2稀释剂中，在283-318 K的温度范围内，通过腔衰荡光谱研究了硝酸根与二甲硫的反应。发现该反应的速率常数k（1）为温度依赖性和压力无关性：k（1）= 4.5（-2.8）（+ 4.0）x 10（-13）exp [（310 +/- 220）/ T] cm（3）分子（-1）s（- 1）。不确定度是回归分析的两个标准偏差。当前的速率常数与Daykin and Wine（Int。J. Chem。Kinet。1990，22，1083）所报道的速率常数非常吻合，可用于大气模型计算。进行了理论计算以验证中间配合物的存在。

著录项

来源
《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2006年第23期|共5页
作者
Nakano Y; Ishiwata T; Aloisio S; Kawasaki M;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
GAS-PHASE REACTIONS; ABSOLUTE RATE CONSTANTS; MARINE BOUNDARY-LAYER; DIMETHYL SULFIDE DMS; CAVITY RING-DOWN; ATMOSPHERIC SULFUR; ORGANIC SULFIDES; CROSS-SECTION; OH; KINETICS;

机译：气相反应;绝对速率常数;海洋边界层;二甲基硫醚DMS;模腔衰荡;大气硫;有机硫化物;截面;OH;动力学;

相似文献

外文文献
中文文献
专利

1. Temperature and pressure dependence of the rate constants of the reaction of NO3 radical with CH3SCH3 [J] . Nakano Y, Ishiwata T, Aloisio S, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2006,第23期

机译：NO3自由基与CH3SCH3反应速率常数的温度和压力依赖性
2. Nonmonotonic Temperature Dependence of the Pressure-Dependent Reaction Rate Constant and Kinetic Isotope Effect of Hydrogen Radical Reaction with Benzene Calculated by Variational Transition-State Theory [J] . Zhang Hui, Zhang Xin, Truhlar Donald G., The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2017,第47期

机译：通过变分过渡 - 状态理论计算氢气自由基反应氢气反应的压力依赖反应速率恒定和动力学同位素效应的非调调温度依赖性
3. Pressure and temperature dependence of the rate constants for the association reactions of vinoxy and 1-methylvinoxy radicals with nitric oxide [J] . Eric Delbos, Pascal Devolder, Lahcen ElMaimouni, Physical chemistry chemical physics: PCCP . 2002,第13期

机译：乙烯基和1-甲基乙烯基氧基与一氧化氮缔合反应速率常数的压力和温度依赖性
4. Pressure and temperature dependence of the reaction of vinyl radical with alkenes II: Measured rates and predicted product distributions for vinyl + propene [C] . C. Franklin Goldsmith, Huzeifa Ismail, Paul R. Abel, Proceedings of the Combustion Institute . 2009

机译：乙烯基与烯烃反应的压力和温度依赖性II：乙烯基+丙烯的测得速率和预测的产物分布
5. Radical competition reactions used to determine the rate constants of some strained cyclopropylcarbinyl radical ring openings and the rate constants of chalcogen transfer for some malononitrile derivatives [D] . Martin-Esker, Amanda Ann. 1993

机译：自由基竞争反应用于确定某些应变的环丙基羰基自由基开环的速率常数和某些丙二腈衍生物的硫族元素转移的速率常数
6. Constant normal pressure constant surface tension and constant temperature molecular dynamics simulation of hydrated 12-dilignoceroylphosphatidylcholine monolayer. [O] . Feng Sun 2002

机译：水合12-二甲基癸二酰基磷脂酰胆碱单层的恒定常压恒定表面张力和恒定温度的分子动力学模拟。
7. Rate constants and temperature dependences for the reactions of hydroxyl radical with several halogenated methanes, ethanes, and propanes by relative rate measurements [O] . DeMore, W. B., Hsu, K.-J. 1995

机译：通过相对速率测量，羟基自由基与几种卤代甲烷，乙烷和丙烷反应的速率常数和温度依赖性
8. Rate Constant and Temperature Dependence for the Reaction of Hydroxyl Radicals with 2-Flouropropane (FC-281ea) and Comparison with an Estimated Rate Constant [R] . DeMore, W., Wilson, E., Jr. 1998

机译：羟基自由基与2-氟丙烷（FC-281ea）反应的速率常数和温度依赖性与估算速率常数的比较

Temperature and pressure dependence of the rate constants of the reaction of NO3 radical with CH3SCH3

摘要

著录项

相似文献

相关主题

期刊订阅