首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Are Halide center dot center dot center dot Halide contacts a feature of rock-salts only?
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Are Halide center dot center dot center dot Halide contacts a feature of rock-salts only?

机译:卤化物中心点中心点中心点卤化物仅与岩盐接触吗?

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The electron density distribution function in the crystalline hydroxylammonium chloride obtained using the high-resolution X-ray diffraction technique was analyzed by means of Bader's "atoms in molecule" theory. The anion-anion interactions in the crystal of this ionic material were examined and the energy of the Cl-center dot center dot center dot Cl- contacts was estimated on the basis of the experimental data. The results obtained coincide well with the theoretical calculations and the X-ray diffraction data for the rock-salts. The existence of such type of interactions was shown to be not the unique feature of inorganic salts with point charge cations.
机译:利用Bader的“分子中的原子”理论分析了使用高分辨率X射线衍射技术获得的结晶性羟基氯化铵晶体中的电子密度分布函数。检查该离子材料的晶体中的阴离子-阴离子相互作用,并基于实验数据估计Cl-中心点中心点中心点Cl-接触的能量。获得的结果与岩石盐的理论计算和X射线衍射数据非常吻合。已证明这种类型相互作用的存在不是具有点电荷阳离子的无机盐的独特特征。

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