Empirical description of chiral autocatalysis

Micskei K; Pota G; Caglioti L; Palyi G

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Empirical description of chiral autocatalysis

机译：手性自催化的经验描述

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摘要

The only known example of chiral autocatalysis is the alkylation of N-heterocyclic aldehydes with iPr(2)Zn (Soai reaction). The mechanism and some details of this reaction are not yet clear. An empirical formula is proposed here for the description of this chiral autocatalytic reaction. This formula allows the calculation of some very informative parameters.

机译：手性自催化的唯一已知例子是N-杂环醛与iPr（2）Zn的烷基化（Soai反应）。该反应的机理和一些细节尚不清楚。在此提出用于描述该手性自催化反应的经验公式。该公式可以计算一些非常有用的参数。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2006年第18期|共3页
作者
Micskei K; Pota G; Caglioti L; Palyi G;
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正文语种 eng
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ASYMMETRIC AUTOCATALYSIS; ENANTIOMERIC EXCESS; KINETIC-MODEL; AMPLIFICATION; PYRIMIDINE-5-CARBALDEHYDE; DIISOPROPYLZINC; ALKANOL;

机译：不对称自催化;对映体过量;动力学模型;放大;嘧啶5-乙醛;二异丙基锌;链烷醇;

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1. Empirical description of chiral autocatalysis [J] . Micskei K, Pota G, Caglioti L, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2006,第18期

机译：手性自催化的经验描述
2. Determination of the absolute structure of the chiral crystal consisting of achiral dibutylhydroxytoluene and asymmetric autocatalysis triggered by this chiral crystal [J] . Matsumoto Arimasa, Takeda Sora, Harada Shunya, Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2016,第19期

机译：确定由非手性二丁基羟基甲苯组成的手性晶体的绝对结构以及由该手性晶体引发的不对称自催化
3. Reversal in enantioselectivity induced by achiral alcohols in asymmetric autocatalysis in the presence of a chiral diol as a chiral initiator [J] . Shibata T., Tarumi H., Kawasaki T., Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry . 2012,第14期

机译：在手性二醇作为手性引发剂存在下，在不对称自催化中由非手性醇诱导的对映选择性逆转
4. Chiral Autocatalysis and Selectivity in the Vicinity of Solid Surfaces [C] . Dilip K. Kondepudi American Chemical Society . 2002

机译：固体表面附近的手性自催化和选择性
5. The Relevance of Contact Terms versus Pion-Exchange Contributions in the Chiral Effective Field Theory Description of Nucleon-Nucleon Scattering [D] . Alanazi, Hamdah. 2021

机译：联系人与沟渠交换贡献的相关性在手性有效场理论中核心核心散射的描述
6. Asymmetric autocatalysis. Chiral symmetry breaking and the origins of homochirality of organic molecules [O] . Kenso SOAI 2019

机译：不对称自催化。手性对称性的破坏和有机分子同手性的起源
7. Discrimination of cryptochirality in chiral isotactic polystyrene by asymmetric autocatalysis† †Electronic supplementary information (ESI) available: The asymmetric autocatalysis induced by bis(phenol) 5. See DOI: 10.1039/b912813a Click here for additional data file. [O] . Kawasaki, Tsuneomi, Hohberger, Christiane, Araki, Yuko, 2009

机译：不对称自催化鉴别手性等规聚苯乙烯中的隐性 †可用电子补充信息（ESI）：由双酚5引起的不对称自催化。请参见DOI：10.1039 / b912813a 单击此处获取其他数据文件。
8. Enantiomeric Recognition of Organic Ammonium Salts by Chiral Dialkyl-, Dialkenyl-, and Tetramethyl-Substituted Pyridino-18-Crown-6 and Tetramethyl-Substituted Bis-Pyridino-18-Crown-6 Ligands: Comparison of Temperature-Dependent 1H NMR and Empirical Force [R] . Bradshaw, J. S., Huszthy, P., McDaniel, C. W., 1990

机译：手性二烷基 - ，二烯基 - 和四甲基 - 取代的吡啶基-18-冠-6和四甲基取代的双吡啶基-18-冠-6配体对有机铵盐的对映体识别：温度依赖的1H NmR和实证力的比较

Empirical description of chiral autocatalysis

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