Inherent pitfalls in the simplified evaluation of kinetic curves

Kormanyos B; Horvath AK; Peintler G; Nagypal I

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Inherent pitfalls in the simplified evaluation of kinetic curves

机译：动力学曲线简化评估中的固有陷阱

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It is shown and explained in detail by four examples generated from known kinetic models that simplified evaluation proceduresinitial rate studies, individual exponential curve fitting method may inherently lead to inappropriate chemical conclusions, even in the case of relatively simple kinetic systems. It is also shown that in the case of all four examples the simultaneous curve fitting immediately reveals the defectiveness of the kinetic model obtained from the simplified evaluation procedures. We therefore propose the extensive usage of the simultaneous curve fitting of all the kinetic traces to avoid these pitfalls and to find the appropriate kinetic models.

机译：它是由从已知动力学模型生成的四个示例详细显示和解释的，这些示例简化了评估程序的初始速率研究，即使在相对简单的动力学系统的情况下，单独的指数曲线拟合方法也可能固有地导致不合适的化学结论。还显示，在所有四个示例的情况下，同时曲线拟合立即揭示了从简化评估程序获得的动力学模型的缺陷。因此，我们建议广泛使用所有动力学轨迹的同时曲线拟合以避免这些陷阱并找到合适的动力学模型。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2007年第33期|共6页
作者
Kormanyos B; Horvath AK; Peintler G; Nagypal I;
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SLIGHTLY ACIDIC MEDIUM; EXTRACTING EXPERIMENTAL INFORMATION; CHLORITE-TETRATHIONATE REACTION; HYPOCHLOROUS ACID; IODIDE REACTION; DETAILED MECHANISM; SELF-INHIBITION; LARGE MATRICES; PERIODATE; ION;

机译：弱酸性介质;提取实验信息;亚氯四甲酸反应;次氯酸;碘化物反应;详细机理;自抑制;大型基质;过碘;离子;

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1. Inherent pitfalls in the simplified evaluation of kinetic curves [J] . Kormanyos B, Horvath AK, Peintler G, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2007,第33期

机译：动力学曲线简化评估中的固有陷阱
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4. Inherent Biases in Reference-based Evaluation for Grammatical Error Correction and Text Simplification [C] . Leshem Choshen, Omri Abend Annual meeting of the Association for Computational Linguistics . 2018

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5. Evaluation of curve-fitting methods for the simultaneous determination of isoenzymes from inhibition kinetic responses. [D] . Fitzpatrick, Carol Peterson. 1990

机译：从抑制动力学响应中同时测定同工酶的曲线拟合方法的评估。
6. A method for limiting pitfalls in the production of enhancement kinetic curves in 3T dynamic magnetic resonance mammography [O] . Eleftherios Lavdas, Panayiotis Mavroidis, Violeta Roka, 2012

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7. The Pitfalls of the Brachial Arterial Pressure Curve in the Evaluation of Valvular Aortic Stenosis [O] . Margherita G. GIULIANI, Lawrence GOULD 1969

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Inherent pitfalls in the simplified evaluation of kinetic curves

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