Evolution of the reaction mechanism during ultrafast photoinduced electron transfer

Kuzmin MG; Soboleva IV; Dolotova EV

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Evolution of the reaction mechanism during ultrafast photoinduced electron transfer

机译：超快光诱导电子转移过程中反应机理的演变

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Specific features of ultrafast photoinduced electron transfer (ET) in concentrated liquid solutions and in neat electron donating solvents are discussed in terms of continuous distribution of ET rate constants, related to electron tunneling with statistical distribution of electronic coupling matrix element and distances between reactant molecules. Available data on photoinduced electron transfer in solutions for several systems are analyzed. Electron tunneling approach is shown to provide global description of nonexponential kinetics of excited states decay at various concentrations of reactant and in neat solvents.

机译：根据ET速率常数的连续分布，讨论了浓缩溶液和纯给电子溶剂中的超快光致电子传递（ET）的特定特征，该速率常数与电子隧穿，电子耦合基质元素的统计分布以及反应物分子之间的距离有关。分析了几种系统溶液中有关光致电子转移的可用数据。显示出电子隧穿方法可提供各种浓度的反应物和纯溶剂中激发态衰减的非指数动力学的整体描述。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2008年第23期|共7页
作者
Kuzmin MG; Soboleva IV; Dolotova EV;
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FREE-ENERGY; SOLVENT; EXCIPLEXES; COMPLEXES; DYNAMICS; REGION; DONOR;

机译：自由能;溶剂;专家;复杂性;动力学;区域;捐助方;

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1. Evolution of the reaction mechanism during ultrafast photoinduced electron transfer [J] . Kuzmin MG, Soboleva IV, Dolotova EV The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2008,第23期

机译：超快光诱导电子转移过程中反应机理的演变
2. Ultrafast photoinduced electron transfer at electrodes: The general case of a heterogeneous electron-transfer reaction (Review) [J] . Gundlach L., Willig F. Chemphyschem: A European journal of chemical physics and physical chemistry . 2012,第12期

机译：电极超快光突出电子转移：非均相电子转移反应的一般情况（审查）
3. Correlated electron-nuclear dynamics in ultrafast photoinduced electron-transfer reactions at dye-semiconductor interfaces [J] . Michael Thoss, Ivan Kondov, Haobin Wang Physical review . 2007,第15期

机译：染料-半导体界面超快光诱导电子转移反应中的相关电子核动力学
4. ULTRAFAST PHOTOINDUCED ELECTRON TRANSFER AND ULTRAFAST PHOTOINDUCED ENERGY TRANSFER: PHOTOSENSORS AND BIOSENSORS FROM SEMICONDUCTING POLYMERS [C] . . -1

机译：超快光诱导的电子转移和超快光诱导的能量转移：来自半导聚合物的光传感器和生物传感器
5. Correlating Electronic and Nuclear Motions in Ultrafast Photoinduced Charge Transfer Reactions with Femtosecond Multidimensional Spectroscopies. [D] . Lynch, Michael Stanley. 2013

机译：飞秒多维光谱法在超快光诱导电荷转移反应中的电子运动和核运动的相关性。
6. Ultrafast photoinduced electron transfer in face-to-face charge-transfer π-complexes of planar porphyrins and hexaazatriphenylene derivatives [O] . Toru Aoki, Hayato Sakai, Kei Ohkubo, 2015

机译：平面卟啉与六氮杂苯并菲衍生物的面对面电荷转移π-络合物中的超快光诱导电子转移
7. Model-free Investigation of Ultrafast Bimolecular Chemical Reactions: Bimolecular Photoinduced Electron Transfer [O] . Bernhard Lang, Arnulf Rosspeintner, Eric Vauthey 2012

机译：无氮抗体型化学反应的无模型调查：双分子光导电
8. Ultrafast photoinduced electron transfer reactions in supramolecular arrays: Studies of electronic coupling and solvation [R] . Wasielewski, M. R., Wiederrecht, G. P., Svec, W. A. 1993

机译：超分子阵列中的超快光诱导电子转移反应：电子耦合和溶剂化的研究

Evolution of the reaction mechanism during ultrafast photoinduced electron transfer

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