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首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Vibrational Relaxation of Highly Vibrationally Excited O3 in Collisions with OH
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Vibrational Relaxation of Highly Vibrationally Excited O3 in Collisions with OH

机译:与OH碰撞时高振动激发O3的振动弛豫

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摘要

We report a theoretical study of highly excited O3 in collisions with vibrationally cold OH.Special emphasis is placed on initial vibrational energies of O3 between 9 and 21 kcal mol~(-1).All calculations have employed the quasiclassical trajectory method and the realistic double many-body expansion potential energy surface for HO4(2A).Many aspects of the title relaxation process are presented.The results indicate that it may not be ignorable in studying the stratospheric ozone budget.
机译:我们报告了与振动的冷OH碰撞中高激发O3的理论研究,特别着重于9至21 kcal mol〜(-1)之间的O3的初始振动能,所有计算均采用了准经典轨迹法和现实的双重方法。研究了HO4(2A)的多体膨胀势能面。研究表明了标题弛豫过程的许多方面。结果表明,在研究平流层臭氧收支方面,它可能是不可忽略的。

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