Comment on Simple KBrO_3, H_2SO_4 Batch Oscillator

Vilmos Gáspár; Richard J. Field

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Comment on Simple KBrO_3, H_2SO_4 Batch Oscillator

机译：评论简单KBrO_3，H_2SO_4批量振荡器

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Rachwalska~1 reported oscillations in redox potential at a Pt-electrode in the well-stirred, aqueous, batch system KBrO_3 and H_2SO_4. The KBtO_3 contained __0.02% Br~- impurity. We are concerned that the experimentally observed oscillations in redox potential result from some form of physical/chemical artifact and should be treated with care. The major cause of our concern is that we see no basis for their occurrence in homogeneous FKN~2 oxybromine chemistry. However, because we have no experimental evidence for our concern, we accept at face value the experimentally observed oscillations. The origin of these oscillations in homogeneous chemical dynamics is supported by Rachwalska~1 using oscillatory simula_tions based on the FKN chemistry, given below using the author's numbering and rate parameters.

机译：Rachwalska〜1报告了在搅拌良好的水性批处理系统KBrO_3和H_2SO_4的Pt电极上氧化还原电势的振荡。 KBtO_3含有__0.02％Br〜-杂质。我们担心实验观察到的氧化还原电势的振荡是由某种形式的物理/化学假象引起的，应谨慎对待。我们关注的主要原因是，我们认为在均相的FKN〜2氧溴化学中它们的存在没有依据。但是，由于我们没有实验证据可以证明我们的关注，因此我们从表面上接受实验观察到的振荡。 Rachwalska〜1使用基于FKN化学的振荡模拟来支持均质化学动力学中这些振荡的起源，以下使用作者的编号和速率参数给出。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2009年第27期|共2页
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Vilmos Gáspár; Richard J. Field;
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1. Comment on Simple KBrO_3, H_2SO_4 Batch Oscillator [J] . Vilmos Gáspár, Richard J. Field The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2009,第27期

机译：评论简单KBrO_3，H_2SO_4批量振荡器
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3. Simple KBrO3, H2SO4 Batch Oscillator [J] . Malgorzata Rachwalska The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2009,第6期

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Comment on Simple KBrO_3, H_2SO_4 Batch Oscillator

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