Influence of Water in the UV-Induced Chemistry of Methanol in the Solid Phase

L. Krim; J. Lasne; C. Laffon; Ph. Parent

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Influence of Water in the UV-Induced Chemistry of Methanol in the Solid Phase

机译：固相中水在紫外线诱导的甲醇化学反应中的影响

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UV-irradiated methanol (CH_3OH) in water ice at 3 K has been investigated with infrared spectroscopy andcompared with pure methanol. The main byproducts detected are formaldehyde (H_2CO), carbon monoxide(CO), carbon dioxide (CO_2), methane (CH_4), and ethylene glycol C_2H_4(OH)_2). The production of H_2CO,CO_2, and CO is enhanced in water ice, resulting from cross reactions between the byproducts of methanolwith those of water (OH and H_2O_2).

机译：通过红外光谱研究了水冰在3 K下的紫外线辐照甲醇（CH_3OH），并与纯甲醇进行了比较。检测到的主要副产物是甲醛（H_2CO），一氧化碳（CO），二氧化碳（CO_2），甲烷（CH_4）和乙二醇C_2H_4（OH）_2）。甲醇副产物与水副产物（OH和H_2O_2）之间的交叉反应导致水冰中H_2CO，CO_2和CO的产生增加。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2009年第31期|共6页
作者
L. Krim; J. Lasne; C. Laffon; Ph. Parent;
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正文语种 eng
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Influence; Water in the UV-Induced Chemistry; Methanol in the Solid Phase;

机译：影响;紫外线诱导化学中的水;固相中的甲醇;

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1. Influence of Water in the UV-Induced Chemistry of Methanol in the Solid Phase [J] . L. Krim, J. Lasne, C. Laffon, The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2009,第31期

机译：固相中水在紫外线诱导的甲醇化学反应中的影响
2. Environmental mobility of cobalt-Influence of solid phase characteristics and groundwater chemistry. [J] . Payne TE, Itakura T, Comarmond MJ Applied radiation and isotopes: including data, instrumentation and methods for use in agriculture, industry and medicine . 2009,第7a8期

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机译：甲醇 - 水洗脱固相萃取柱的替代方法，用于在水性环境样品中分离高Log K（亚子）有机化合物

Influence of Water in the UV-Induced Chemistry of Methanol in the Solid Phase

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