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Rotational analysis for the doppler-free photoelectron spectrum of water using the spectator model

机译:使用观众模型对水的无多普勒光电子谱进行旋转分析

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摘要

A photoelectron spectrum of H_2O has been recorded at a resolution of 2 meV under Doppler-free conditions. Complex rotational structures appear in the individual vibrational states of the electronic X? ~(+ 2)B_1 and ?~(+ 2)A_2 states in H_2O~+. The rotational structures are analyzed and well reproduced using a spectator orbital model developed for rotationally resolved photoelectron spectroscopy.
机译:在无多普勒条件下,以2 meV的分辨率记录了H_2O的光电子光谱。复杂的旋转结构出现在电子X?的各个振动状态中。 H_2O〜+中的〜(+ 2)B_1和?〜(+ 2)A_2状态。使用为旋转分辨光电子能谱开发的旁观者轨道模型分析并很好地复制了旋转结构。

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