Theoretical treatment of redox processes involving lanthanide(II) compounds: Reactivity of organosamarium(II) and organothulium(II) complexes with CO_2 and pyridine

Labouille S.; Nief F.; Maron L.

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Theoretical treatment of redox processes involving lanthanide(II) compounds: Reactivity of organosamarium(II) and organothulium(II) complexes with CO_2 and pyridine

机译：涉及镧系元素（II）化合物的氧化还原过程的理论处理：有机sa（II）和有机th（II）配合物与CO_2和吡啶的反应性

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An effective methodology to deal with the theoretical treatment on the redox chemistry of divalent organolanthanide complexes is reported and has been tested on two representative substrates, pyridine and CO_2, with two different metals (samarium and thulium). An influence of the ancillary ligands, namely, C_5Me_5 (Cp) or (2,3,4,5-tetramethylphospholyl) (Tmp), on the one- or two-electron oxidation processes is observed. The theoretical results are in excellent agreement with the experimental observations indicating the efficiency of the method.

机译：报道了一种有效的方法来处理对二价有机镧系元素络合物的氧化还原化学的理论处理，并已在两种代表性的底物吡啶和CO_2上使用两种不同的金属（sa和th）进行了测试。观察到辅助配体，即C_5Me_5（Cp）或（2,3,4,5-四甲基膦酰基）（Tmp），对单电子或两电子氧化过程的影响。理论结果与实验结果非常吻合，表明了该方法的有效性。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2011年第29期|共7页
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Labouille S.; Nief F.; Maron L.;
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1. Theoretical treatment of redox processes involving lanthanide(II) compounds: Reactivity of organosamarium(II) and organothulium(II) complexes with CO_2 and pyridine [J] . Labouille S., Nief F., Maron L. The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2011,第29期

机译：涉及镧系元素（II）化合物的氧化还原过程的理论处理：有机sa（II）和有机th（II）配合物与CO_2和吡啶的反应性
2. Transition-Metal-Promoted C-N Bond-Formation Processes - Low-Spin Fe~(III), Fe~(II), and Ni~(II) Complexes of 2-[(Arylamido)phenylazo]pyridine - X-ray Structure, Redox- and Spectroelectrochemistry [J] . Amrita Saha, Partha Majumdar, Shie-Ming Peng, European journal of inorganic chemistry . 2000,第12期

机译：过渡金属促进的CN键形成过程-2-[（（Arylamido）phenylazoazo] pyridine）的低旋Fe〜（III），Fe〜（II）和Ni〜（II）配合物-X射线结构，氧化还原-和光谱电化学
3. Carboxylate-free Mn~(III)_2Ln~(III)_2 (Ln = lanthanide) and Mn~(III)_2Y~(III)_2 complexes from the use of (2-hydroxymethyl)pyridine: Analysis of spin frustration effects [J] . Papatriantafyllopoulou C., Abboud K.A., Christou G. Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第18期

机译：使用（2-羟甲基）吡啶制得的无羧酸盐的Mn〜（III）_2Ln〜（III）_2（Ln =镧系元素）和Mn〜（III）_2Y〜（III）_2配合物：旋转挫折效应的分析
4. Experimental and Theoretical Studies onBiologically Active Lanthanide (III) Complexes [C] . I. Kostova, N. Trendafilova, I. Georgieva, International Conference on Perspectives in Vibrational Spectroscopy . 2008

机译：生物活性镧系元素（III）复合物的实验和理论研究
5. Part I. Syntheses and characterization of hydrogen-bridged lanthanide(II)-boron complexes. Part II. Syntheses and characterization of cyanide-bridged lanthanide(III)-palladium complexes. [D] . Lim, Soyoung. 2001

机译：第一部分：氢桥联镧系元素（II）-硼配合物的合成与表征。第二部分氰化物桥联的镧系元素（III）-钯配合物的合成与表征。
6. Crystal structures of two isotypic lanthanide(III) complexes: triaqua26-diacetylpyridine bis(benzoylhydrazone)methanollanthanide(III) trichloride methanol disolvates (LnIII = Tb and Dy) [O] . Chihiro Kachi-Terajima, Norihisa Kimura 2018

机译：两种同型镧系元素（III）配合物的晶体结构：三水合26-二乙酰基吡啶双（苯甲酰基）三氯呋喃三酐（III）甲醇二溶剂化物（LnIII = Tb和Dy）
7. Reversible Sm(III)/Sm(II) Redox Chemistry of an Organosamarium(III) Complex [O] . -1

机译：可逆SM（III）/ SM（II）有机冈（III）复合物的氧化还原化学
8. Lanthanide (III) Catalyzed Reactions: Structure and Thermodynamics ofIntermediate Complexes, and Implications for Reactivity [R] . Huskens, J. 1994

机译：镧系元素（III）催化反应：中间体配合物的结构和热力学，以及反应性的影响

Theoretical treatment of redox processes involving lanthanide(II) compounds: Reactivity of organosamarium(II) and organothulium(II) complexes with CO_2 and pyridine

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