Adducts of alcohols with ethers: The rotational spectrum of isopropanol-dimethyl ether

Evangelisti L.; Pesci F.; Caminati W.

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Adducts of alcohols with ethers: The rotational spectrum of isopropanol-dimethyl ether

机译：醇与醚的加成物：异丙醇-二甲醚的旋转光谱

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The rotational spectra of three isotopologues of the isopropanol-dimethyl ether molecular complex have been measured with pulsed jet Fourier transform microwave spectroscopy. In the complex, isopropanol acts as a proton donor and takes a gauche conformation. The H → D isotopic substitution of the hydroxylic hydrogen participating in the O-H???O hydrogen bond produces an increase of the B and C rotational constants, according to the shrinkage of the O???O distance of about 7 m?, underlying and sizing the associated Ubbelohde effect.

机译：异丙醇-二甲醚分子配合物的三种同位素的旋转光谱已通过脉冲喷射傅立叶变换微波光谱法进行了测量。在该络合物中，异丙醇充当质子供体并具有gauche构象。参与OH-O氢键的羟基氢的H→D同位素取代使B和C旋转常数增加，这是由于O-O距离缩小约7 m 2所致。并调整相关的乌伯洛德效应。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2011年第34期|共4页
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Evangelisti L.; Pesci F.; Caminati W.;
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1. Adducts of alcohols with ethers: The rotational spectrum of isopropanol-dimethyl ether [J] . Evangelisti L., Pesci F., Caminati W. The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2011,第34期

机译：醇与醚的加成物：异丙醇-二甲醚的旋转光谱
2. Conformational equilibria in adducts of alcohols with ethers: The rotational spectrum of ethylalcohol-dimethylether [J] . Evangelisti L., Feng G., Rizzato R., Chemphyschem: A European journal of chemical physics and physical chemistry . 2011,第10期

机译：醇与醚加成物的构象平衡：乙醇-二甲醚的旋转光谱
3. Adducts of Xenon with Organic Molecules: Rotational Spectrum of Dimethyl Ether-Xe [J] . Laura B. Favero, Biagio Velino, Aldo Millemaggi, Chemphyschem: A European journal of chemical physics and physical chemistry . 2003,第8期

机译：氙与有机分子的加合物：二甲基醚-Xe的旋转光谱
4. Stereochemistry on the Formation of Syringylglycerol-8-O-4'-(Sinapyl Alcohol) Ether from Sinapyl Alcohol with Enzyme Preparations of Eucommia ulmoides [C] . Shameul Alam, Takeshi Katayama, Toshisada Suzuki International Symposium on Wood Science and Technology（IAWPS 2008）(国际木材产品学会联合会2008学术研讨会) . 2008

机译：杜仲杜仲的酶法制备自Sinapyl醇形成Syringylglycerol-8-O-4'-（Sinapyl Alcohol）醚的立体化学
5. VIBRATION - ROTATION SPECTRA OF DIMETHYL ETHER AND DIMETHYL ETHER-D(6). [D] . DUNCAN, BUDD L. 1970

机译：二甲醚和二甲醚-D（6）的振动-旋转光谱。
6. Comparison of clinical results for the use of ethyl acetate and diethyl ether in the formalin-ether sedimentation technique performed on polyvinyl alcohol-preserved specimens. [O] . L S Garcia, R Shimizu 1981

机译：在保存了聚乙烯醇的标本上进行福尔马林-醚沉淀技术中使用乙酸乙酯和乙醚的临床结果比较。
7. Shape of the Adduct Formic AcidDimethyl Ether: A Rotational Study [O] . -1

机译：加合物甲酸二甲醚的形状：旋转研究

Adducts of alcohols with ethers: The rotational spectrum of isopropanol-dimethyl ether

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