Matrix isolation spectroscopic and theoretical study of carbon dioxide activation by titanium oxide molecules

Zhuang J.; Li Z.H.; Fan K.; Zhou M.

首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Matrix isolation spectroscopic and theoretical study of carbon dioxide activation by titanium oxide molecules

【24h】

Matrix isolation spectroscopic and theoretical study of carbon dioxide activation by titanium oxide molecules

机译：基质分离光谱和氧化钛分子活化二氧化碳的理论研究

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The reactions of titanium monoxide and dioxide molecules with carbon dioxide were investigated by matrix isolation infrared spectroscopy. It was found that the titanium monoxide molecule is able to activate carbon dioxide to form the titanium dioxide-carbon monoxide complex upon visible light excitation via a weakly bound TiO(η ~1-OCO) intermediate in solid neon. In contrast, the titanium dioxide molecule reacted with carbon dioxide to form the titanium monoxide-carbonate complex spontaneously on annealing. Theoretical calculations predicted that both activation processes are thermodynamically exothermic and kinetically facile.

机译：用基质隔离红外光谱法研究了一氧化钛和二氧化钛分子与二氧化碳的反应。发现一氧化钛分子能够通过固体氖中的弱结合的TiO（η〜1-OCO）中间体在可见光激发下活化二氧化碳以形成二氧化钛-一氧化碳络合物。相反，二氧化钛分子与二氧化碳在退火时自发形成一氧化钛-碳酸盐复合物。理论计算预测，两种活化过程在热力学上都是放热的，在动力学上也很容易。

著录项

来源
《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2012年第13期|共8页
作者
Zhuang J.; Li Z.H.; Fan K.; Zhou M.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词

相似文献

外文文献
中文文献
专利

1. Matrix isolation spectroscopic and theoretical study of carbon dioxide activation by titanium oxide molecules [J] . Zhuang J., Li Z.H., Fan K., The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2012,第13期

机译：基质分离光谱和氧化钛分子活化二氧化碳的理论研究
2. Matrix isolation spectroscopic and theoretical study of dihydrogen activation by group v metal dioxide molecules [J] . Zhou M., Wang C., Zhuang J., The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2011,第1期

机译：Ⅴ族金属氧化物分子对二氢活化的基质分离光谱和理论研究
3. Methane Activation by Titanium Monoxide Molecules:A Matrix Isolation Infrared Spectroscopic and Theoretical Study [J] . Guanjun Wang, Yu Gong, Mohua Chen, Journal of the American Chemical Society . 2006,第17期

机译：一氧化钛分子对甲烷的活化作用：基质分离红外光谱和理论研究
4. Modification of low-density polyethylene based activated carbon using titanium dioxide for carbon monoxide and hydrocarbon adsorption [C] . Yuliusman, Mega Puspita Sari, Azmia Rizka Nafisah International Symposium on Applied Chemistry . 2019

机译：用二氧化钛进行二氧化碳和烃吸附的低密度聚乙烯基活性炭的改变
5. First-principles theoretical studies of titanium dioxide(110) surfaces and silicon(100)/silicon dioxide interfaces. [D] . Ng, Kwok-On (Keith). 1999

机译：二氧化钛（110）表面和硅（100）/二氧化硅界面的第一原理理论研究。
6. Activated carbon/titanium dioxide composite to adsorb volatile organic compounds associated with human body odor [O] . Takeshi Hara, Haruna Nabei, Ayumi Kyuka 2020

机译：活性炭/二氧化钛复合物吸附与人体气味相关的挥发性有机化合物
7. Methane Activation by Titanium Monoxide Molecules: A Matrix Isolation Infrared Spectroscopic and Theoretical Study [O] . -1

机译：甲烷激活钛一氧化钛分子：基质隔离红外光谱和理论研究
8. Theoretical Studies of Atmospheric Triatomic Molecules: 'Ab initio' Equations of Motion Excitation Energies for Valence States of the Configuration 1 Pi 3 Gerade 2 Pi 1-Ungerade in Excited Carbon Dioxide. [R] . England, W., Yeager, D., Wahl, A. C. 1976

机译：大气三原子分子的理论研究：配位1 pi 3 Gerade 2 pi 1-Ungerade在激发二氧化碳中的价态的“从头算”运动激发能。

Matrix isolation spectroscopic and theoretical study of carbon dioxide activation by titanium oxide molecules

摘要

著录项

相似文献

相关主题

期刊订阅