首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Molecular-Beam Optical Stark and Zeeman Study of the [17.8]0~+? X~1Σ~+ (0,0) Band System of AuF
【24h】

Molecular-Beam Optical Stark and Zeeman Study of the [17.8]0~+? X~1Σ~+ (0,0) Band System of AuF

机译:[17.8] 0〜+?的分子束光学斯塔克和塞曼研究AuF的X〜1Σ〜+(0,0)波段系统

获取原文
获取原文并翻译 | 示例
           

摘要

The [17.8]0~+?X~1Σ~+ (0,0) band of gold monofluoride, AuF, has been recorded at a resolution of 40 MHz both field free and in the presence of a static electric and magnetic field. The observed Stark shifts were analyzed to determine the permanent electric dipole moment, μel, of 2.03 ± 0.05 D and 4.13 ± 0.02 D, for the [17.8]0~+(v = 0) and X~1Σ~+(v = 0) states, respectively. The small magnetic tuning observed for the [17.8]0~+(v = 0) state is attributed to rotational and magnetic field mixing with the [17.7]1 state and has been successfully modeled using an effective Hamiltonian for the 3Π state. A comparison with the numerous published theoretical predictions is made.
机译:单氟化金[A7.8]的[17.8] 0〜+?X〜1Σ〜+(0,0)谱带以40 MHz的分辨率记录在无场且有静电和磁场的情况下。分析观察到的斯塔克位移,确定[17.8] 0〜+(v = 0)和X〜1Σ〜+(v = 0)的永久电偶极矩μel为2.03±0.05 D和4.13±0.02D。 )状态。在[17.8] 0〜+(v = 0)状态下观察到的小磁调谐归因于与[17.7] 1状态发生的旋转和磁场混合,并且已经使用有效的哈密顿量对3Π状态进行了建模。与大量已发表的理论预测进行了比较。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱:kefu@zhangqiaokeyan.com

京公网安备:11010802029741号 ICP备案号:京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有
  • 客服微信

  • 服务号