首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >High-resolution study of ~(13)C~(16)O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL: Revised term values
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High-resolution study of ~(13)C~(16)O A-X(v' = 0-9) bands using the VUV-FTS at SOLEIL: Revised term values

机译:使用VUV-FTS在SOLEIL对〜(13)C〜(16)O A-X(v'= 0-9)波段进行的高分辨率研究:修正的项值

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摘要

We present high-resolution absorption spectral measurements of the A ~1Π-X~1Σ~+ band system of ~(13)C~(16)O. These were recorded with the VUV Fourier transform spectrometer (VUV-FTS) installed on the DESIRS beamline at the SOLEIL synchrotron. This work includes revised term values that extend to higher J' values than previous measurements for most v' levels and lower J' values for v' = 0. We confirm previously observed perturbations of the rotational levels in greater detail and present evidence for new perturbations. The accuracy in the wavelength determination and term values is on average within 0.01 cm ~(-1), improving upon previous measurements.
机译:我们提出了〜(13)C〜(16)O的A〜1Π-X〜1Σ〜+带系统的高分辨率吸收光谱测量。用安装在SOLEIL同步加速器上DESIRS光束线上的VUV傅立叶变换光谱仪(VUV-FTS)记录这些。这项工作包括修订后的项值,对于大多数v'级,其术语扩展到比以前的测量值更高的J'值,而对于v'= 0时,其J'值更低。 。波长确定和项值的准确度平均在0.01 cm〜(-1)以内,在以前的测量中有所提高。

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