Photodissociation Spectroscopy of the Anionic Copper Nitrate Association Complex Cu(NO_3)_3~-

Sydney H. Kaufman; J. Mathias Weber

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Photodissociation Spectroscopy of the Anionic Copper Nitrate Association Complex Cu(NO_3)_3~-

机译：阴离子硝酸铜缔合配合物Cu（NO_3）_3〜-的光解离光谱

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We report the UV photodissociation spectrum of mass-selected Cu(NO_3)_3~-ions at photon energies between 3.0 and 5.6 eV. Upon photon absorption,→NO_3·Cu(NO_3)_3~-undergoes reductive dissociation losing neutral NO_3 and resulting in the formation of Cu(NO_3)_2~-. The experimental results are discussed and interpreted with the aid of quantum-chemical calculations. The parent ion is calculated to have C_2 symmetry with a strongly distorted octahedral coordination around the Cu ion. Time-dependent density functional theory is used to describe the accessible electronic transitions, which can be characterized as ligand-to-metal charge transfer transitions from the nitrate ligands to the copper ion.

机译：我们报告了质量选择的Cu（NO_3）_3〜-离子在3.0至5.6 eV之间的光子能量下的紫外光解离光谱。在吸收光子后，→NO_3·Cu（NO_3）_3〜发生还原离解，失去中性NO_3，形成Cu（NO_3）_2〜-。通过量子化学计算讨论和解释了实验结果。计算出母离子具有C_2对称性，并且在Cu离子周围具有严重扭曲的八面体配位。随时间变化的密度泛函理论用于描述可访问的电子跃迁，其特征可以是从硝酸盐配体到铜离子的配体到金属的电荷转移跃迁。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2014年第41期|共5页
作者
Sydney H. Kaufman; J. Mathias Weber;
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正文语种 eng
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Photodissociation Spectroscopy; the UV photodissociation; photodissociation spectrum;

机译：光解离光谱;紫外光解离;光解离光谱;

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1. Photodissociation Spectroscopy of the Anionic Copper Nitrate Association Complex Cu(NO_3)_3~- [J] . Sydney H. Kaufman, J. Mathias Weber The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2014,第41期

机译：阴离子硝酸铜缔合配合物Cu（NO_3）_3〜-的光解离光谱
2. Thermochemical Study of Complexation and Solvation in the p-Alanine-Cu(NO_3)_2-Water-Ethanol System: 2. Enthalpies of Solvation of Sodium Alaninate and Copper(II) Nitrate in Mixed Solvents [J] . V. N. Vandyshev, S. F. Ledenkov Russian Journal of Inorganic Chemistry . 2011,第10期

机译：对丙氨酸-Cu（NO_3）_2-水-乙醇体系中络合和溶剂化的热化学研究：2.混合溶剂中铝酸钠和硝酸铜（II）的溶剂化焓
3. Copper(II) Nitrate Ammoniates Cu(NH_3)_4(NO_3)_2 and Cu(NH_3)_2(NO_3)_2 and Their Thermolysis under Reduced Pressure [J] . S.S.Dyukarev, Y.M.Korenev Russian Journal of Inorganic Chemistry . 1999,第6期

机译：硝酸铜（II）氨化物Cu（NH_3）_4（NO_3）_2和Cu（NH_3）_2（NO_3）_2及其在减压下的热分解
4. Nitrate (NO_3~-) Prediction in Soil Analysis using Near-infrared (NIR) Spectroscopy [C] . M. S. Amirul, R. Endut, C. B. M. Rashidi, International Conference on Applied Photonics and Electronics . 2020

机译：近红外（NIR）光谱法测定土壤分析中的硝酸盐（NO_3〜 - ）预测
5. Photodissociation Spectroscopy of Anionic Transition Metal Complexes. [D] . Kaufman, Sydney Hamilton. 2013

机译：阴离子过渡金属配合物的光解离光谱。
6. L-edge X-ray Absorption Spectroscopy and DFT Calculations on Cu2O2 Species: Direct Electrophilic Aromatic Attack by Side-on Peroxo Bridged Dicopper(II) Complexes [O] . Munzarin F. Qayyum, Ritimukta Sarangi, Kiyoshi Fujisawa, -1

机译：L2边缘X射线吸收光谱和Cu2O2物种的DFT计算：侧向过氧桥联Dicopper（II）配合物的直接亲电芳香攻击
7. 63Cu NMR Spectroscopy of Copper(I) Complexes with Various Tridentate Ligands: CO as a Useful 63Cu NMR Probe for Sharpening 63Cu NMR Signals and Analyzing the Electronic Donor Effect of a Ligand [O] . -1

机译：63Cu铜（I）铜（I）复合物的铜（I）配合物，具有各种三齿配体：CO作为用于锐化63Cu NMR信号的有用的63CU NMR探针，并分析配体的电子供体效应

Photodissociation Spectroscopy of the Anionic Copper Nitrate Association Complex Cu(NO_3)_3~-

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