...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory >Multiedge X-ray Absorption Spectroscopy Part II: XANES Analysis of Bridging and Terminal Chlorides in Hexachlorodipalladate(II) Complex
【24h】

Multiedge X-ray Absorption Spectroscopy Part II: XANES Analysis of Bridging and Terminal Chlorides in Hexachlorodipalladate(II) Complex

机译：多边缘X射线吸收光谱法第二部分：六氯二palladate（II）配合物中桥接和末端氯化物的XANES分析

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相似文献
  • 相关主题

摘要

X-ray absorption spectroscopy is a unique experimental technique that can provide ground state electronic structure information about transition metal complexes with unoccupied d-manifold. The quantitative treatments of pre-edge and rising-edge features have already been developed for the sulfur- and chlorine-ligand K-edge excitations. The complementarity of using multiple core excitation edges from hard, tender, and soft X-ray energy regions has been defined for the first paper of this series. The given study provides compelling evidence for the transferability of the empirical transition dipole integral from ligand K-edge to metal L-edge and back to ligand K-edge in the tender X-ray energy range. The case study was performed for a series of homoleptic chloropalladium compounds at the chlorine K- and palladium L-edges. We propose the method described here to be generally applicable for other core level excitations, where complementarity of ground state electronic structural information from XANES analysis can provide the complete electronic structure description.
机译：X射线吸收光谱法是一种独特的实验技术，可以提供有关具有未占用d流形的过渡金属配合物的基态电子结构信息。对于硫和氯配体K边缘激发，已经开发了对前边缘和上升边缘特征的定量处理。对于本系列的第一篇论文，已经定义了使用来自硬，柔和和软X射线能量区域的多个核心激发边的互补性。给出的研究为在柔和的X射线能量范围内从配体K边缘到金属L边缘再回到配体K边缘的经验跃迁偶极积分的可转移性提供了令人信服的证据。对氯K和钯L边缘的一系列均相氯钯化合物进行了案例研究。我们建议这里描述的方法通常适用于其他核心能级激励，其中来自XANES分析的基态电子结构信息的互补性可以提供完整的电子结构描述。

著录项

相似文献

  • 外文文献
  • 中文文献
  • 专利
获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号