Formation of the Hydroxyl Radical by Radiative Association

Svensson S. Karl-Mikael; Gustafsson Magnus; Nyman Gunnar

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Formation of the Hydroxyl Radical by Radiative Association

机译：通过辐射缔合形成羟基自由基

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The reaction rate constant for the radiative association of O(P-3) and H(S-2) has been calculated by combining a few different methods and taking account of both direct and resonance-mediated pathways. The latter includes both shape resonances and Feshbach type inverse predissociation. The reaction rate constant is expressed as a function of temperature in the interval 10-30000 K. This reaction may be astrochemically relevant and is expected to be of use in astrochemical networks.

机译：O（P-3）和H（S-2）的辐射缔合反应速率常数是通过结合几种不同的方法并考虑到直接和共振介导的途径来计算的。后者包括形状共振和Feshbach型逆预分解。反应速率常数表示为温度的函数，介于10-30000 K之间。该反应在化学上可能是相关的，预计将在化学网络中使用。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2015年第50期|共7页
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Svensson S. Karl-Mikael; Gustafsson Magnus; Nyman Gunnar;
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1. Formation of the Hydroxyl Radical by Radiative Association [J] . Svensson S. Karl-Mikael, Gustafsson Magnus, Nyman Gunnar The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2015,第50期

机译：通过辐射缔合形成羟基自由基
2. Effects of trans-resveratrol on copper-dependent hydroxyl-radical formation and DNA damage: Evidence for hydroxyl-radical scavenging and a novel, glutathione-sparing mechanism of action [J] . Burkitt MJ., Duncan J. Archives of Biochemistry and Biophysics . 2000,第2期

机译：反式白藜芦醇对铜依赖性羟基自由基形成和DNA损伤的影响：羟基自由基清除的证据和新型的谷胱甘肽保留作用机制。
3. Neutrophil degranulation inhibits potential hydroxyl-radical formation. Relative impact of myeloperoxidase and lactoferrin release on hydroxyl-radical production by iron-supplemented neutrophils assessed by spin-trapping techniques [J] . B E Britigan, D J Hassett, D R Hamill, The biochemical journal . 1989,第2期

机译：中性粒细胞脱粒抑制潜在的羟基自由基形成。通过自旋捕集技术评估髓过氧化物酶和乳铁蛋白释放对补充铁的中性粒细胞产生羟自由基的相对影响
4. Electrochemical generation of hydroxyl radicals for hydroxyl radical footprinting experiments [C] . Eric B. Monroe, Michael L. Heien American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2013

机译：羟基自由基的电化学产生羟基自由基脚印实验
5. Shock tube measurements of methyl radical+molecular oxygen kinetics and the heat of formation of the hydroxyl radical. [D] . Herbon, John Thomas. 2004

机译：冲击管测量的是甲基自由基+分子氧动力学和羟基自由基的形成热。
6. Neutrophil degranulation inhibits potential hydroxyl-radical formation. Relative impact of myeloperoxidase and lactoferrin release on hydroxyl-radical production by iron-supplemented neutrophils assessed by spin-trapping techniques. [O] . B E Britigan, D J Hassett, G M Rosen, 1989

机译：中性粒细胞脱粒抑制潜在的羟基自由基形成。脊髓过氧化物酶和乳铁蛋白释放对铁补充的中性粒细胞产生的羟自由基产生的相对影响通过自旋捕集技术评估。
7. Effect of Plant Phenolics on the Formation of the Spin-Adduct of Hydroxyl Radical and the DNA Strand Breaking by Hydroxyl Radical. [O] . Kazuyuki HIRAMOTO, Natsuko OJIMA, Ken-ichi SAKO, 1996

机译：植物酚类对羟基自由基旋转加合物形成的影响，羟基自由基断裂。
8. Autoxidative Cytotoxicity: Is There Metal-Independent Formation of Hydroxyl Radicals. Are There Crypto-Hydroxyl Radicals [R] . Borg, D. C., Schaich, K. M., Forman, A. 1983

机译：自氧化细胞毒性：是否存在与金属无关的羟基自由基形成。有加密羟基自由基

Formation of the Hydroxyl Radical by Radiative Association

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