Temperature and Pressure Dependence of the Reaction S plus CS ( plus M) -  CS2 (+M)

Glarborg Peter; Marshall Paul; Troe Juergen

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Temperature and Pressure Dependence of the Reaction S plus CS ( plus M) - CS2 (+M)

机译：反应S + CS（+ M）-> CS2（+ M）的温度和压力依赖性

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Experimental data for the unimolecular decomposition of CS2 from the literature are analyzed by unimolecular rate theory with the goal of obtaining rate constants for the reverse reaction S + CS (+M) -> CS2 (+M) over wide temperature and pressure ranges. The results constitute an important input for the kinetic modeling of CS2 oxidation. CS2 dissociation proceeds as a spin-forbidden process whose detailed properties are still not well understood. The role of the singlet triplet transition involved is discussed.

机译：通过单分子速率理论分析了文献中CS2单分子分解的实验数据，目的是在较宽的温度和压力范围内获得逆反应S + CS（+ M）-> CS2（+ M）的速率常数。结果为CS2氧化动力学模型的重要输入。 CS2的解离过程是自旋禁止过程，其详细性质仍未得到很好的理解。讨论了单重态三重态转变的作用。

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《The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory》 |2015年第28期|共5页
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Glarborg Peter; Marshall Paul; Troe Juergen;
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1. Temperature and Pressure Dependence of the Reaction S plus CS ( plus M) - CS2 (+M) [J] . Glarborg Peter, Marshall Paul, Troe Juergen The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory . 2015,第28期

机译：反应S + CS（+ M）-> CS2（+ M）的温度和压力依赖性
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Temperature and Pressure Dependence of the Reaction S plus CS ( plus M) - CS2 (+M)

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