Thermodynamics and Kinetics in Micellar Media. Reaction of the Hydroxide Ion with 1,3,5-Trinitrobenzene in Aqueous Solutions of a Neutral Nonionic Surfactant. Effect of the Concentration of Background Electrolyte

M. Le Gall; J. Lelievre; A. Loppinet-Serani; P. Letellier

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Thermodynamics and Kinetics in Micellar Media. Reaction of the Hydroxide Ion with 1,3,5-Trinitrobenzene in Aqueous Solutions of a Neutral Nonionic Surfactant. Effect of the Concentration of Background Electrolyte

机译：胶束介质中的热力学和动力学。氢氧化物离子与1,3,5-三硝基苯在中性非离子表面活性剂的水溶液中的反应。背景电解质浓度的影响

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The use of a neutral surfactant (Brij 35) allows us to investigate its influence upon the kinetics of the reaction between a neutral substrate and a charged reactant. The thermodynamic description of a micellar system can be obtained by introducing a variable of area in the expression of the internal energy. Thus, the content of micellar solutions is separated into two components: a volume content associated with dimension 3, and an area content associated with dimension 2. The volume is an extensive parameter and a homogeneous function of degree unity of its content, but the area is not necessarily an extensive function and does not vary linearly with content. In this way, we can describe the evolutionn of the behavior of micellar solutions when the concentration of surfactant increases. We introduce the notion of "micellar catalysis" in terms of an increase of the exchange rate at equilibrium, ~mv_0, for the studied reaction. The formal separation of the content of the solution into two components with different dimensions leads us to suppose a difference in reactivity. The exchange rate associated with the content of dimension 2 equals 40 times the one associated with the content of dimension 3.

机译：使用中性表面活性剂（Brij 35）使我们能够研究其对中性底物与带电反应物之间反应动力学的影响。胶束系统的热力学描述可以通过在内部能量的表达中引入面积变量来获得。因此，胶束溶液的含量分为两个部分：与尺寸3相关的体积含量和与尺寸2相关的面积含量。体积是其内容的统一参数和度统一的齐次函数，但面积不一定是扩展功能，并且不会随内容线性变化。这样，我们可以描述表面活性剂浓度增加时胶束溶液行为的演变。我们引入“胶束催化”的概念，即增加所研究反应在平衡时的交换速率〜mv_0。将溶液内容物正式分为两个不同尺寸的组分，这使我们假设反应性有所不同。与维度2的内容相关联的汇率等于与维度3的内容相关联的汇率的40倍。

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《The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical》 |2003年第33期|共8页
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M. Le Gall; J. Lelievre; A. Loppinet-Serani; P. Letellier;
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1. Thermodynamics and Kinetics in Micellar Media. Reaction of the Hydroxide Ion with 1,3,5-Trinitrobenzene in Aqueous Solutions of a Neutral Nonionic Surfactant. Effect of the Concentration of Background Electrolyte [J] . M. Le Gall, J. Lelievre, A. Loppinet-Serani, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2003,第33期

机译：胶束介质中的热力学和动力学。氢氧化物离子与1,3,5-三硝基苯在中性非离子表面活性剂的水溶液中的反应。背景电解质浓度的影响
2. Determination of chlorine content in 1,3,5-triamino-2,4,6-trinitrobenzene by converting it into 1,3,5-trihydroxy-2,4,6-trinitrobenzene by treatment with aqueous sodium hydroxide [J] . Mehilal., Surve RN., Agrawal JP., The Analyst: The Analytical Journal of the Royal Society of Chemistry: A Monthly International Publication Dealing with All Branches of Analytical Chemistry . 1998,第2期

机译：氢氧化钠水溶液转化为1,3,5-三羟基-2,4,6-三硝基苯，测定1,3,5-三氨基-2,4,6-三硝基苯中的氯含量
3. Effect of the Nature of Background Electrolyte on the Thermodynamic Characteristics of the Acid–Base Reactions of L-Asparagine in Aqueous Solutions [J] . Russian Journal of Physical Chemistry . 2019,第9期

机译：背景电解质性质对水溶液中L-天冬酰胺酸碱反应热力学特性的影响
4. Modeling Concentration and Temperature Dependence of Thermodynamic Properties of Aqueous Electrolyte Solutions: Investigation of K+, Cl-,SO4-2,H2O System [C] . Sanjoy Bhattacharia, Chau-Chyun Chen Annual conference of the North American Thermal Analysis Society . 2014

机译：电解质水溶液热力学性质的浓度和温度依赖性建模：K +，Cl-，SO4-2，H2O系统的研究
5. Kinetics of free radical reactions generated by laser flash photolysis of hydroxide(-) + chloride(-) and sulfate(-) + chloride(-) in the aqueous phase: Chemical mechanism, kinetics data and their implications. [D] . Yu, Xiaoying. 2001

机译：水相中氢氧化物（-）+氯化物（-）和硫酸盐（-）+氯化物（-）的激光快速光解产生的自由基反应动力学：化学机理，动力学数据及其意义。
6. Kinetic Evidence for Near Irreversible Nonionic Micellar Entrapment of N-(2′-Methoxyphenyl)phthalimide (1) under the Typical Alkaline Reaction Conditions [O] . M. Niyaz Khan, Yoke-Leng Sim, Azhar Ariffin -1

机译：N-（2-甲氧基苯基）邻苯二甲酰亚胺（1）在典型的碱性反应条件下几乎不可逆的非离子胶束截留的动力学证据
7. Effect of Cationic Micellar Reaction Field on Reaction Kinetics of Meisenheimer σ-Complex Formation between 1,3,5-Trinitrobenzene and Hydroxide Ion [O] . Matsui Rie, Ikeda Yoshiyuki, Sasaki Muneo, 2007

机译：阳离子胶束反应场对1,3,5-三硝基苯与氢氧化物离子形成meisenheimerσ-配合物反应动力学的影响

Thermodynamics and Kinetics in Micellar Media. Reaction of the Hydroxide Ion with 1,3,5-Trinitrobenzene in Aqueous Solutions of a Neutral Nonionic Surfactant. Effect of the Concentration of Background Electrolyte

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