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首页> 外文期刊>The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical >Low-Frequency Dielectric Dispersion in Colloidal Suspensions of Uncharged Insulating Particles
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Low-Frequency Dielectric Dispersion in Colloidal Suspensions of Uncharged Insulating Particles

机译:不带电绝缘粒子胶体悬浮液中的低频介电弥散

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摘要

The standard electrokinetic equations for a spherical uncharged insulating particle suspended in a binary electrolyte solution with an applied ac electric field are analytically solved in the general case when both the ion diffusion coefficients and valences have arbitrary values.It is shown that under these conditions,the field-induced ion density profiles extend at low frequencies at far larger distances from the particle than in the case when both -diffusion coefficients have the same value.The corresponding induced charge density modifies the dipolar coefficient,leading to an additional low-frequency dielectric dispersion.
机译:当离子扩散系数和化合价都具有任意值时,通常情况下,可以通过解析方法求解在交流电场作用下悬浮在二元电解质溶液中的球形不带电绝缘粒子的标准电动方程。研究表明,在这些条件下,与两个扩散系数具有相同值的情况相比,场致离子密度分布在低频处的扩展距离与粒子的距离要大得多。相应的感应电荷密度会修改偶极系数,从而导致额外的低频介电弥散。

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