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Hybrid materials for solid-state dye laser applications

机译:固态染料激光应用的混合材料

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摘要

The quest for a solid-state tunable dye laser can be satisfied by sol-gel prepared organic-inorganic hybrids. A photostability study of porous silica-Rhodamine 6G hybrids prepared via a sol-gel method is presented. The dye molecules can be incorporated into the silica matrix by forming weak or covalent bonds (hybrids of classes I and II, respectively). New class II samples and traditional class I materials prepared by the predoping method were synthesized. Samples were characterized by photoluminescence measurements to compare the emission properties and the photostability of the samples. The decay of the fluorescence signal as the cumulative excitation energy increases is reported and interpreted by hypothesizing that the dye molecules can be hosted in different surroundings within the porous glass matrix. The reported photoluminescence and photobleaching features indicate the class II samples as good candidates for solid-state dye lasers.
机译:溶胶-凝胶制备的有机-无机杂化物可以满足对固态可调染料激光器的需求。提出了通过溶胶-凝胶法制备的多孔二氧化硅-若丹明6G杂化物的光稳定性研究。可以通过形成弱键或共价键(分别为I和II类杂化物)将染料分子掺入二氧化硅基质中。合成了通过预掺杂方法制备的新的II类样品和传统的I类材料。通过光致发光测量来表征样品,以比较样品的发射性质和光稳定性。通过假设染料分子可以存在于多孔玻璃基质内的不同环境中,报告并解释了随着累积激发能的增加荧光信号的衰减。报道的光致发光和光漂白特性表明II类样品是固态染料激光器的良好候选者。

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