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首页> 外文期刊>The journal of physical chemistry, C. Nanomaterials and interfaces >Probing Disordered Structure and Tube-Tube Interaction in Carbon Nanotubes by Scanning Transmission X-ray Microscopy
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Probing Disordered Structure and Tube-Tube Interaction in Carbon Nanotubes by Scanning Transmission X-ray Microscopy

机译:通过扫描透射X射线显微镜探测碳纳米管中的无序结构和管-管相互作用。

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摘要

The electronic structure of individual carbon nanotubes (CNTs) with different diameters has been investigated by scanning transmission X-ray microscopy (STXM). Various factors that may alter the STXM spectral features in CNT bundles have been discussed. Tube diameter has been found to be proportional to the spectral intensity, whereas it has negligible effect on the spectral shape. Disordered structure in CNTs introduced in the synthesis process was observed, which significantly affected the X-ray absorption spectrum by a reduction of the π* excitation. Moreover, tube—tube interaction in CNT bundles was detected, which can enhance the π* excitation. Insights into the nature of CNT bundles with various electronic structures may provide a new vision to understand the performance of CNT-based devices.
机译:通过扫描透射X射线显微镜(STXM)研究了具有不同直径的单个碳纳米管(CNT)的电子结构。已经讨论了可能改变CNT束中STXM光谱特征的各种因素。已发现管直径与光谱强度成正比,而对光谱形状的影响可忽略不计。观察到在合成过程中引入的CNT中的无序结构,这通过减少π*激发显着影响了X射线吸收光谱。此外,检测到CNT束中的管对管相互作用,这可以增强π*激发。洞察具有各种电子结构的CNT束的性质可能会为了解基于CNT的设备的性能提供新的视野。

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