Ag Nanoparticles Decorated Small-Sized AgTCNQF4 Nanorod: Synthesis in Aqueous Solution and Its Photoinduced Charge Transfer Reactions

Jing Wang; Weiqing Xu; Junjie Zhang

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Ag Nanoparticles Decorated Small-Sized AgTCNQF4 Nanorod: Synthesis in Aqueous Solution and Its Photoinduced Charge Transfer Reactions

机译：银纳米粒子修饰小型AgTCNQF4纳米棒：水溶液中的合成及其光诱导的电荷转移反应

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A kind of functional noble metal nanoparticles and metal/organic semiconductor composite nanomaterials, Ag nanoparticles (AgNPs, 6—10 nm in diameter) decorated small-sized Ag-tetracyano-p-tetrafluoroquinodimethane (AgTCNQF4) nanorods (150—400 nm in length and 60—100 nm in diameter), have been successfully synthesized through a rapid microemulsion reaction between TCNQF4 molecules and an AgNP colloid under a soft template of poly(ethylene glycol)-block-poly(propylene glycol)-block-poly(ethylene glycol). The morphology, chemical structure, and elemental composition of the prepared AgNPs—AgTCNQF4 composite nanorods were studied by transmission electron microscopy, selected-area electron diffraction, and X-ray photoelectron spectroscopy. The real-time ultraviolet—visible spectroscopy assisted with two-dimensional correlation spectroscopic analysis was employed to explore the growth of AgNPs—AgTCNQF4 composite nanorods in microemulsion.

机译：Ag纳米颗粒（直径为6-10 nm）是一种功能性的贵金属纳米颗粒和金属/有机半导体复合纳米材料，装饰有尺寸较小的Ag-四氰基-对-四氟喹二甲烷（AgTCNQF4）纳米棒（长度为150-400 nm），在柔软的聚乙二醇-嵌段-聚丙二醇-嵌段-聚乙二醇模板下，TCNQF4分子与AgNP胶体之间通过快速微乳化反应成功合成了直径60-100 nm）。通过透射电子显微镜，选择区域电子衍射和X射线光电子能谱研究了制备的AgNPs-AgTCNQF4复合纳米棒的形貌，化学结构和元素组成。实时紫外-可见光谱结合二维相关光谱分析，探讨了AgNPs-AgTCNQF4复合纳米棒在微乳液中的生长。

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《The journal of physical chemistry, C. Nanomaterials and interfaces》 |2014年第42期|共9页
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Jing Wang; Weiqing Xu; Junjie Zhang;
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1. Ag Nanoparticles Decorated Small-Sized AgTCNQF4 Nanorod: Synthesis in Aqueous Solution and Its Photoinduced Charge Transfer Reactions [J] . Jing Wang, Weiqing Xu, Junjie Zhang The journal of physical chemistry, C. Nanomaterials and interfaces . 2014,第42期

机译：银纳米粒子修饰小型AgTCNQF4纳米棒：水溶液中的合成及其光诱导的电荷转移反应
2. Enhanced charge transfer activity in Au nanoparticles decorated ZnO nanorods photoanode [J] . Iwantono Iwantono, Saad Siti Khatijah Md, Anggelina Fera, Physica, E. Low-dimensional systems & nanostructures . 2019,第期

机译：AU纳米粒子的增强电荷转移活动装饰ZnO Nanorods PhotoNode
3. Sensitive and selective chloroform sensor using Fe_2O_3 nanoparticle-decorated ZnO nanorods in an aqueous solution [J] . Haslinda Abdul Hamid, Zainovia Lockman, Toshiaki Hattori, Journal of materials science . 2019,第20期

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4. Photoinduced Electron Transfer Reactions,Magnetic Field Effects on the Decay Process of Charge-Separated State,and Time-Resolved EPR Spectra in Fullerene-Donor Systems [C] . Hiroaki Yonemura, Shinya Moribe, Norihiro Kuroda, The Meeting of the Electrochemical Society . 2003

机译：光抑制电子转移反应，对富勒烯 - 供体系统中的电荷分离状态衰减过程的磁场效应，以及富勒烯 - 供体系统中的时间分辨的EPR光谱
5. Mechanistic and stereochemical studies of photoinduced electron transfer cyclization reactions: The role of nitrogen. The aqueous Prins reaction and efforts towards the total synthesis of (+)-dactylolide. [D] . Aubele, Danielle L. 2004

机译：光致电子转移环化反应的机理和立体化学研究：氮的作用。 Prins水溶液反应并努力全合成（+）-二羟甲基内酯。
6. Reaction Mechanism for Direct Proton Transfer from Carbonic Acid to a Strong Base in Aqueous Solution I: Acid and Base Coordinate and Charge Dynamics [O] . Snehasis Daschakraborty, Philip M. Kiefer, Yifat Miller, -1

机译：质子从碳酸直接转移至强碱在水溶液中的反应机理I：酸与碱的配位及电荷动力学
7. Mechanistic and Stereochemical Studies of Photoinduced Electron Transfer Initiated Cyclization Reactions: The Role of Nitrogen. The Aqueous Prins Reaction and Efforts Towards the Total Synthesis of (+)-Dactylolide [O] . Aubele Danielle L. 2004

机译：光诱导电子转移引发环化反应的机理和立体化学研究：氮的作用。 Prins水溶液的反应及其对（+）-Dactylolide的全合成的努力
8. Ultrafast photoinduced electron transfer reactions in supramolecular arrays: From charge separation and storage to molecular switches [R] . Wasielewski, M R 1992

机译：超分子阵列中的超快光诱导电子转移反应：从电荷分离和储存到分子开关

Ag Nanoparticles Decorated Small-Sized AgTCNQF4 Nanorod: Synthesis in Aqueous Solution and Its Photoinduced Charge Transfer Reactions

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