Novel H _2 activation by a tris[3,5-bis(trifluoromethyl)phenyl] borane frustrated Lewis pair

Herrington T.J.; Thom A.J.W.; White A.J.P.; Ashley A.E.

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Novel H _2 activation by a tris[3,5-bis(trifluoromethyl)phenyl] borane frustrated Lewis pair

机译：由三[3,5-双（三氟甲基）苯基]硼烷挫败的路易斯对的新型H _2活化

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Tris[3,5-b is(trifluoromethyl)phenyl]borane (1, BArF _(18)), has been synthesised on a practical scale for the first time. According to the Gutmann-Beckett method it is a more powerful Lewis acid than B(C _6F _5) _3. It forms a 'frustrated Lewis pair' with 2,2,6,6-tetramethylpiperidine which cleaves H _2 to form a salt containing the novel anion [μ-H(BArF _(18)) _2] ~-.

机译：Tris [3,5-b is（trifluoromethyl）phenyl] borane（1，BArF _（18）），是首次在实际规模上合成。根据Gutmann-Beckett方法，它是一种比B（C -6F _5）_3更强的路易斯酸。它与2,2,6,6-四甲基哌啶形成一个“沮丧的路易斯对”，后者会裂解H _2形成含有新型阴离子[μ-H（BArF _（18））_2]〜-的盐。

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《Dalton transactions: An international journal of inorganic chemistry》 |2012年第30期|共4页
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Herrington T.J.; Thom A.J.W.; White A.J.P.; Ashley A.E.;
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1. Novel H _2 activation by a tris[3,5-bis(trifluoromethyl)phenyl] borane frustrated Lewis pair [J] . Herrington T.J., Thom A.J.W., White A.J.P., Dalton transactions: An international journal of inorganic chemistry . 2012,第30期

机译：由三[3,5-双（三氟甲基）苯基]硼烷挫败的路易斯对的新型H _2活化
2. Exploring structural and electronic effects in three isomers of tris{bis(trifluoromethyl)phenyl)borane: towards the combined electrochemical-frustrated Lewis pair activation of H-2 [J] . Blagg Robin J., Lawrence Elliot J., Resner Katie, Dalton transactions: An international journal of inorganic chemistry . 2016,第14期

机译：探索三{双（三（三氟甲基）苯基）硼烷的三种异构体的结构和电子效应：对H-2的电化学受阻的路易斯对活化
3. Heterolytic Cleavage of Dihydrogen by "Frustrated Lewis Pairs" Comprising Bis(2,4,6-tris(trifluoromethyl)phenyl)borane and Amines: Stepwise versus Concerted Mechanism [J] . Zhenpin Lu, Zhonghua Cheng, Zhenxia Chen Angewandte Chemie . 2011,第51期

机译：双（2,4,6-三（三氟甲基）苯基）硼烷和胺的“受阻路易斯对”对氢的异质裂解：逐步与协同机理
4. Development of a soft ionization technique in nonpolar liquid with lithium tetrakis(3,5-bis(trifluoromethyl)-phenyl)borate [C] . A. Takamizawa, N. Niizuma, T. Korenaga American Society for Mass Spectrometry Conference on Mass Spectrometry and Allied Topics . 2012

机译：用锂四锂（3,5-双（三氟甲基） - 苯基）硼酸盐的非极性液体软离子化技术的研制
5. 'Frustrated' Lewis pairs: From Lewis acid-base adducts to the reversible, metal-free activation of hydrogen. [D] . Welch, Gregory Charles. 2008

机译：“沮丧的”路易斯对：从路易斯酸碱加合物到可逆的无金属氢活化。
6. Geminal bis-borane formation by borane Lewis acid induced cyclopropyl rearrangement and its frustrated Lewis pair reaction with carbon dioxide [O] . Yun-Lin Liu, Gerald Kehr, Constantin G. Daniliuc, 2017

机译：硼烷刘易斯酸诱导双丙基硼烷形成双环烷烃并引起环丙基重排及其与二氧化碳的路易斯对偶反应
7. Exploring structural and electronic effects in three isomers of tris{bis(trifluoromethyl)phenyl}borane: Towards the combined electrochemical-frustrated Lewis pair activation of H2 [O] . Blagg, Robin J., Lawrence, Elliot J., Resner, Katie, 2016

机译：探索三{双（三（三氟甲基）苯基}硼烷的三个异构体的结构和电子效应：向H2的电化学受阻的路易斯对结合活化
8. Trityl Tetrakis(3,5-bis(Trifluoromethyl)Phenyl)-Borate: A New Hydride AbstractionReagent [R] . Boudjouk, P., Bahr, S. R. 1992

机译：Trityl Tetrakis（3,5-双（三氟甲基）苯基） - 硼酸盐：一种新的氢化物提取试剂

Novel H _2 activation by a tris[3,5-bis(trifluoromethyl)phenyl] borane frustrated Lewis pair

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