Hydrogen bonded anion ribbons, networks and clusters and sulfur-anion interactions in novel radical cation salts of BEDT-TTF with sulfamate, pentaborate and bromide

Brooks A.C.; Martin L.; Day P.; Lopes E.B.; Almeida M.; Kikuchi K.; Fujita W.; Sasamori K.; Aktusu H.; Wallis J.D.

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Hydrogen bonded anion ribbons, networks and clusters and sulfur-anion interactions in novel radical cation salts of BEDT-TTF with sulfamate, pentaborate and bromide

机译：BEDT-TTF新型自由基阳离子盐与氨基磺酸盐，五硼酸盐和溴化物中的氢键结合的阴离子带，网络和簇以及硫阴离子的相互作用

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The novel radical cation salt (BEDT-TTF)3(sulfamate) _2·2H_2O (BEDT-TTF = bis(ethylenedithio) tetrathiafulvalene) is semiconducting with donor stacks comprised of pairs of partially oxidized molecules and a single more highly oxidized molecule which is twisted out of the stack by ca. 30°. Hydrogen bonded pairs of sulfamate ions are linked into parallel ribbons by further hydrogen bonding between sulfamates and bridging water molecules. In contrast, the BEDT-TTF salt with pentaborate contains infinite layers formed of a network of hydrogen bonded pentaborate anions. Two new bromide salts of BEDT-TTF are reported, one is a semiconducting 1:1 salt in which the bromide is integrated among the BEDT-TTF donors, while the other contain a square of four bromide ions linked together by hydrogen bonding to a centrally located H_5O_2 ~+ cation for every five BEDT-TTF molecules.

机译：新型自由基阳离子盐（BEDT-TTF）3（氨基磺酸盐）_2·2H_2O（BEDT-TTF =双（乙撑二硫代）四硫富瓦烯）与供体叠层半导体化，该供体叠层由成对的部分氧化分子和一个扭曲程度更高的单个分子组成从堆栈中移出30°。氨基磺酸根离子的氢键对通过氨基磺酸根与桥连的水分子之间的进一步氢键连接成平行带。相反，含五硼酸盐的BEDT-TTF盐包含无限层，该层由氢键合的五硼酸盐阴离子网络形成。报道了两种新的BEDT-TTF溴化物盐，一种是半导体1：1盐，其中溴化物整合在BEDT-TTF供体中，而另一种则包含通过氢键连接到中心的四个溴离子的正方形每五个BEDT-TTF分子中有H_5O_2〜+阳离子存在。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第18期|共10页
作者
Brooks A.C.; Martin L.; Day P.; Lopes E.B.; Almeida M.; Kikuchi K.; Fujita W.; Sasamori K.; Aktusu H.; Wallis J.D.;
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正文语种 eng
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BEDT-TTF; sulfur-anion; semiconducting;

机译：BEDT-TTF;硫负离子;半导体;

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1. Hydrogen bonded anion ribbons, networks and clusters and sulfur-anion interactions in novel radical cation salts of BEDT-TTF with sulfamate, pentaborate and bromide [J] . Brooks A.C., Martin L., Day P., Dalton transactions: An international journal of inorganic chemistry . 2013,第18期

机译：BEDT-TTF新型自由基阳离子盐与氨基磺酸盐，五硼酸盐和溴化物中的氢键结合的阴离子带，网络和簇以及硫阴离子的相互作用
2. pH Dependent Formation of Unprecedented Water-Bromide Cluster in the Bromide Salts of PTP Assisted by Anion-π Interactions: Synthesis, Structure, and DFT Study [J] . Prankrishna Manna, Saikat Kumar Seth, Antonio Bauza?, Crystal growth & design . 2014,第2期

机译：阴离子-π相互作用辅助的PTP溴酸盐中前所未有的水-溴簇的pH依赖性形成：合成，结构和DFT研究
3. Hydrogen bonds in radical cation salts of TTF(CH2OH)(4): First complete series with the octahedral rhenium cluster anions [Re6S8-nCl6+n](n-4) (n=0, 1, 2, 3) [J] . Perruchas S, Boubekeur K, Batail P Crystal growth & design . 2005,第4期

机译：TTF（CH2OH）（4）的自由基阳离子盐中的氢键：与八面体rh簇阴离子[Re6S8-nCl6 + n]（n-4）的第一个完整系列（n = 0，1，2，3）
4. SPECTRAL AND ELECTROPHYSICAL PROPERTIES OF ANION-RADICAL SALTS OF TCNQ AND METHYL-TCNQ WITH N-ALKYLPIRAZINIUM CATIONS [C] . Andrey V. Kravchenko, Vladimir A. Starodub, Alexander R. Kazachkov, NATO Advanced Research Workshop on Frontiers in Spectroscopy of Emerging Materials: Recent Advances toward New Technologies . 2004

机译：用N-烷基吡啶鎓阳离子的TCNQ和甲基-TCNQ阴离子盐的光谱和电神法性质
5. The synthesis and physical studies of tetracyanoquinodimethane and tetrafluorotetracyanoquinodimethane based anion radical salts and methyl -substituted tetrathiotetracene and tetraselenotetracene based cation radical salts. [D] . Maruo, Toshio. 1990

机译：基于四氰基喹二甲烷和四氟四氰基喹二甲烷的阴离子自由基盐以及甲基取代的四硫并四苯并四硒代痕量阳离子阳离子盐的合成和物理研究。
6. Crystalline Peroxosolvates: Nature of the Coformer Hydrogen-Bonded Networks and Clusters Intermolecular Interactions [O] . Alexander G. Medvedev, Andrei V. Churakov, Petr V. Prikhodchenko, 2021

机译：结晶过氧溶剂化物：Coformer的性质氢键网络和簇分子间相互作用
7. Hydrogen bonded anion ribbons, networks and clusters and sulfur–anion interactions in novel radical cation salts of BEDT-TTF with sulfamate, pentaborate and bromide [O] . Brooks, AC, Martin, L, Day, P, 2013

机译：BEDT-TTF的新型自由基阳离子盐与氨基磺酸盐，五硼酸盐和溴化物中的氢键结合的阴离子带，网络和簇以及硫阴离子的相互作用
8. Importance of weak hydrogen bonding C-H--donor and C-H--anion interactions in governing the structural properties of organic donors BEDT-TTF and BEDO-TTF and their charge-transfer salts. [R] . Whangbo, M. H., Jung, D., Ren, J., 1989

机译：弱氢键C-H - 供体和C-H - 阴离子相互作用在控制有机供体BEDT-TTF和BEDO-TTF及其电荷转移盐的结构性质中的重要性。

Hydrogen bonded anion ribbons, networks and clusters and sulfur-anion interactions in novel radical cation salts of BEDT-TTF with sulfamate, pentaborate and bromide

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