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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Group 4 metallocene catalysed full dehydrogenation of hydrazine borane
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Group 4 metallocene catalysed full dehydrogenation of hydrazine borane

机译:4族茂金属催化肼硼烷的完全脱氢

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A study of the full dehydrogenation of hydrazine borane (H _2N-NH_2·BH_3) to give H_2 and N_2 as gaseous products catalysed by a variety of group 4 metallocene alkyne complexes of the type Cp'2M(L)(η~2-Me _3SiC_2SiMe_3) (Cp' = substituted or unsubstituted η~5-cyclopentadienyl; M = Ti, no L; M = Zr, L = pyridine) and group 4 metallocene hydrides is presented. Volumetric data show that the amount of hydrogen released is strongly dependent on both, the metal and the cyclopentadienyl ligand.
机译:肼硼烷(H _2N-NH_2·BH_3)完全脱氢以得到H_2和N_2为气态产物的研究,该反应由各种类型为Cp'2M(L)(η〜2-Me)的第4组茂金属炔烃配合物催化_3SiC_2SiMe_3)(Cp′=取代或未取代的η〜5-环戊二烯基; M = Ti,无L; M = Zr,L =吡啶)和第4族茂金属氢化物。体积数据表明,释放的氢气量强烈依赖于金属和环戊二烯基配体。

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