Triad and cyclic diad compounds of [60]fullerene with metallocenes

Mancel D.; Jevric M.; Davies E.S.; Schr?der M.; Khlobystov A.N.

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Triad and cyclic diad compounds of [60]fullerene with metallocenes

机译：[60]富勒烯与茂金属的三元和环状二元化合物

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Metallocene-bridged [60]fullerene triads and cyclised metallocene-[60] fullerene diads are formed via [3 + 2] cycloaddition reactions of [60]fullerene with metallocene dialdehyde and an amino acid. In the case of cyclic diads only one regioisomer is formed, as determined by UV-vis and NMR spectroscopic studies. These compounds have both electron donor (metallocene) and acceptor ([60]fullerene) components and give three electrochemically reversible one-electron reductions for each [60]fullerene moiety. For the ferrocene-containing compounds, an electrochemically reversible one-electron oxidation process is observed, with an irreversible oxidation observed for the ruthenocene analogues.

机译：茂金属桥联的[60]富勒烯三单元和环化的茂金属-[60]富勒烯双单元是通过[60]富勒烯与茂金属二醛和氨基酸的[3 + 2]环加成反应形成的。通过UV-vis和NMR光谱研究确定，在环状二单元组的情况下，仅形成一种区域异构体。这些化合物具有电子给体（茂金属）和受体（[60]富勒烯）成分，并为每个[60]富勒烯部分提供三个电化学可逆的单电子还原。对于含二茂铁的化合物，观察到电化学可逆的单电子氧化过程，而对于钌茂茂类似物观察到不可逆的氧化。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第14期|共12页
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Mancel D.; Jevric M.; Davies E.S.; Schr?der M.; Khlobystov A.N.;
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1. Triad and cyclic diad compounds of [60]fullerene with metallocenes [J] . Mancel D., Jevric M., Davies E.S., Dalton transactions: An international journal of inorganic chemistry . 2013,第14期

机译：[60]富勒烯与茂金属的三元和环状二元化合物
2. Synthesis of Diads and Triads Derived from Carotenoids and Fullerene C60 [J] . Molecules . 2000,第3期

机译：类胡萝卜素和富勒烯C60衍生的Dia和Triad的合成
3. Electronic Interactions and Photoinduced Electron Transfer in Covalently Linked Porphyrin-C_(60)(pyridine) Diads and Supramolecular Triads Formed by Self-Assembling the Diads and Zinc Porphyrin [J] . Francis DSouza, Gollapalli R. Deviprasad, Melvin E. Zandler, The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2002,第19期

机译：共价连接的卟啉-C_（60）（吡啶）diads和自组装的diadia和卟啉锌形成的超分子三元组中的电子相互作用和光诱导电子转移
4. Sodium Ion Effect on Photoinduced Electron Transfer of Porphyrin-Crown Ether-Affixed Quaterthiophene-60Fullerene Triad as a Gated Molecular Switch [C] . Yasuyuki Araki, Huimin Zhang, Osamu Ito, Meeting of the Electrochemical Society . 2007

机译：钠离子效应对卟啉 - 冠醚 - 固定的Quattertheophene-60富勒烯三合会作为门控分子开关的光致电子转移
5. Photoremediation of Organic Compounds with Fullerene (C 60) Modified Tio2 Nanoparticles [D] . Patey, Raymond 2018

机译：富勒烯（C 60）修饰的Tio2纳米粒子对有机化合物的光修复
6. Synthesis of Photoresponsive Dual NIR Two-Photon Absorptive 60Fullerene Triads and Tetrads [O] . Seaho Jeon, Min Wang, Loon-Seng Tan, 2013

机译：光响应双近红外双光子吸收性60富勒烯三联体和四联体的合成
7. Synthesis of Diads and Triads Derived from Carotenoids and Fullerene C60 [O] . Devens Gust, Thomas A. Moore, Ana Moore, 2000

机译：由类胡萝卜素和富勒烯C60衍生的二元和三元组合物

Triad and cyclic diad compounds of [60]fullerene with metallocenes

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