An unprecedented polyoxometalate-based hybrid solid constructed from a neutral metal-organic macrocycle and Dawson polyoxotungstate anions

Xu Y.; Gao Y.; Wei W.; Wang Z.; Li S.; Hu C.

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An unprecedented polyoxometalate-based hybrid solid constructed from a neutral metal-organic macrocycle and Dawson polyoxotungstate anions

机译：由中性金属-有机大环化合物和道森多氧钨酸根阴离子构成的前所未有的基于多金属氧酸盐的杂化固体

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The self-assembly procedure of a Dawson-type polyoxotungstate with pyridine-2,6-dicarboxylate (H_2pdc) and copper~(II) ions produces an exquisite supramolecular aggregation. In the structure, a neutral cucurbit[n]uril-like metal-organic macrocycle is formed of six copper centers and six pdc~(2-) ligands, while a pair of Dawson-type polyoxotungstates are linked to the bottom and top portals of this macrocycle at the joint with the alkali metal ions. A control experiment was carried out to produce a different metalloligand-supported hybrid (instead of the metallomacrocycle) to verify the structure-directing role of Dawson polyanions in the title compound. In addition, the photoluminescent and magnetic properties of the hybrid solid have also been investigated.

机译：Dawson型聚氧钨酸盐与2,6-二羧酸吡啶（H_2pdc）和铜（II）离子的自组装过程产生了精细的超分子聚集。在该结构中，一个中性葫芦状的[n]尿嘧啶样金属有机大环由六个铜中心和六个pdc〜（2-）配体形成，而一对Dawson型多氧钨酸盐连接到该化合物的底部和顶部门这个大环在与碱金属离子的结合处。进行了对照实验，以产生不同的金属配体负载的杂化物（而不是金属大环化合物），以验证道森聚阴离子在标题化合物中的结构指导作用。另外，还研究了杂化固体的光致发光和磁性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第15期|共4页
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Xu Y.; Gao Y.; Wei W.; Wang Z.; Li S.; Hu C.;
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1. An unprecedented polyoxometalate-based hybrid solid constructed from a neutral metal-organic macrocycle and Dawson polyoxotungstate anions [J] . Xu Y., Gao Y., Wei W., Dalton transactions: An international journal of inorganic chemistry . 2013,第15期

机译：由中性金属-有机大环化合物和道森多氧钨酸根阴离子构成的前所未有的基于多金属氧酸盐的杂化固体
2. A novel Wells-Dawson polyoxometalate-based metal-organic framework constructed from the uncommon in-situ transformed bi(triazole) ligand and azo anion [J] . Wang Xiuli, Rong Xing, Lin Hongyan, Inorganic Chemistry Communications . 2016,第Null期

机译：一种新颖的Wells-Dawson多金属氧酸盐基金属有机骨架，由罕见的原位转化双（三唑）配体和偶氮阴离子构成
3. A novel polyoxometalate-based metal-organic compound constructed from an unprecedented [Ag-8(Hpyttz)(4)(H(2)pyttz)(2)] cluster and an in-situ [VW12O40](3-) anion [J] . Wang Xiuli, Chen Lufei, Liu Guocheng, Inorganic Chemistry Communications . 2015,第Null期

机译：一种新型的基于多金属氧酸盐的金属有机化合物，由前所未有的[Ag-8（Hpyttz）（4）（H（2）pyttz）（2）]簇和原位[VW12O40]（3-）阴离子构成
4. The effects of pH values on the solid-state electrochemistry of Wells-Dawson-type mono-aluminum-subsutituted polyoxotungstate [C] . Ko Shibata, Jun Matsui, Hideki Nabika 日本化学会春季年会講演予稿集 . 2018

机译：pH值对井 - 道森型单铝型多氧化术多氧化铝固态电化学的影响
5. Adaptive self-assembly and induced-fit transformations of anion-binding metal-organic macrocycles [O] . Ting Zhang, Li-Peng Zhou, Xiao-Qing Guo, -1

机译：阴离子结合金属有机大环的自适应自组装和诱导拟合转换
6. Efficient Preparation of Functionalized Hybrid Organic/Inorganic Wells-Dawson-type Polyoxotungstates [O] . -1

机译：高效制备官能化杂种有机/无机井-AWSON型多氧钨酸盐
7. Macrocycles Containing Tin. Solid Complexes of Anions Encrypted in Macrobicyclic Lewis Acidic Hosts [R] . Newcomb, M., Horner, J. H., Blanda, M. T., 1989

机译：含有锡的大环。在macrobicyclic Lewis酸性主体中加密的阴离子固体配合物

An unprecedented polyoxometalate-based hybrid solid constructed from a neutral metal-organic macrocycle and Dawson polyoxotungstate anions

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