Keggin type mono Ni(ii)-substituted phosphomolybdate: A sustainable, homogeneous and reusable catalyst for Suzuki-Miyaura cross-coupling

Pathan S.; Patel A.

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Keggin type mono Ni(ii)-substituted phosphomolybdate: A sustainable, homogeneous and reusable catalyst for Suzuki-Miyaura cross-coupling

机译：Keggin型单Ni（ii）取代的磷钼酸盐：铃木-宫浦交叉偶联的可持续，均质和可重复使用的催化剂

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Keggin type mono Ni(ii)-substituted phosphomolybdate was synthesized and characterized by various physico-chemical techniques and used as a catalyst for Suzuki-Miyaura cross-coupling. The influence of different reaction parameters was studied, to get the maximum yield. The novelty of the present work lies in obtaining >97% yield of biphenyl in 14 h under mild reaction conditions. Although the present catalyst is homogeneous, it was regenerated and reused up to two cycles. Results demonstrated that the catalyst was effective and sustainable for cross-coupling of various halobenzenes with phenylboronic acid in aqueous medium.

机译：合成了Keggin型单Ni（ii）取代的磷钼酸盐，并通过各种物理化学技术对其进行了表征，并将其用作Suzuki-Miyaura交叉偶联的催化剂。研究了不同反应参数的影响，以获得最大的收率。本研究的新颖之处在于在温和的反应条件下，在14小时内可获得> 97％的联苯收率。尽管本发明的催化剂是均相的，但将其再生并重复使用多达两个循环。结果表明，该催化剂对于水性介质中各种卤代苯与苯基硼酸的交叉偶联是有效且可持续的。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第32期|共7页
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Pathan S.; Patel A.;
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Ni(ii)-substituted phosphomolybdate; homogeneous; reusable catalyst;

机译：Ni（ii）-取代的磷钼酸盐;均质;可重复使用的催化剂;

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1. Keggin type mono Ni(ii)-substituted phosphomolybdate: A sustainable, homogeneous and reusable catalyst for Suzuki-Miyaura cross-coupling [J] . Pathan S., Patel A. Dalton transactions: An international journal of inorganic chemistry . 2013,第32期

机译：Keggin型单Ni（ii）取代的磷钼酸盐：铃木-宫浦交叉偶联的可持续，均质和可重复使用的催化剂
2. Two Keggin compounds constructed from tri -/tetra-nuclear Cu clusters linked mono copper(II)-substituted phosphomolybdates [J] . Tian Aixiang, Ni Huaiping, Tian Yan, Inorganic Chemistry Communications . 2016,第Null期

机译：由三核/四核铜团簇构成的两种Keggin化合物连接单铜（II）取代的磷钼酸盐
3. Pd(II) supported dioxime functionalized Fe3O4 nanoparticles as efficient, eco-friendly and reusable catalysts for the Suzuki-Miyaura cross-coupling reaction in water [J] . Kilic Ahmet, Gezer Esra, Durap Feyyaz, Journal of Organometallic Chemistry . 2019,第期

机译：PD（II）支持二氧化官能化Fe3O4纳米颗粒，作为铃木宫达交叉偶联反应的高效，环保和可重复使用的催化剂
4. Hybrid catalysts compose of mono-substituted Keggin-polyoxometalate and different aminopyridine derivatives as catalysts for oxidation of benzyl alcohol with hydrogen peroxide [C] . Lijuan Chen, Tao Feng, Pengfei Wang, International Conference on Chemical Engineering and Advanced Materials . 2012

机译：杂交催化剂组成单替代的Keggin-聚毒酸盐和不同的氨基吡啶衍生物，作为氧化苄醇与过氧化氢氧化的催化剂
5. Part A: Coordination of pyridine and pyridine-type ligands to cobalt(II)- and cobalt(III)-substituted Keggin and Dawson-type heteropolyanions. Part B: Encapsulation of various heteropolyanions in artificial phospholipid vesicles: Effects of size, charge, and polarity on encapsulation efficiency. [D] . Samonte, Joseph Laurito. 1996

机译：A部分：吡啶和吡啶型配体与钴（II）和钴（III）取代的Keggin和Dawson型杂多阴离子的配位。 B部分：在人工磷脂囊泡中包裹各种杂多阴离子：大小，电荷和极性对包裹效率的影响。
6. Corrigendum: Green and Facile Synthesis of Metal-Organic Framework Cu-BTC-Supported Sn (II)-Substituted Keggin Heteropoly Composites as an Esterification Nanocatalyst for Biodiesel Production [O] . Qiuyun Zhang, Dan Ling, Dandan Lei, 2020

机译：勘误：绿色有机合成铜-BTC负载的Sn（II）取代的Keggin杂多复合材料作为生物柴油生产的酯化纳米催化剂
7. N-Alkoxycarbonyl / carbamoylmethyl substituted 1H-imidazol-2-yliden-Pd (II) complexes as highly efficient catalysts for Suzuki-Miyaura cross-coupling reaction [O] . Meliha ÇETİN KORUKÇU 2021

机译：N-烷氧基羰基/氨基甲酰基取代的1H-咪唑-2- yliden-PD（II）配合物作为铃木 - 宫系交叉偶联反应的高效催化剂

Keggin type mono Ni(ii)-substituted phosphomolybdate: A sustainable, homogeneous and reusable catalyst for Suzuki-Miyaura cross-coupling

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