Bright orange/red-emitting rhodium(iii) and iridium(iii) complexes: Tridentate N^C^N-cyclometallating ligands lead to high luminescence efficiencies

Gildea L.F.; Batsanov A.S.; Williams J.A.G.

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Bright orange/red-emitting rhodium(iii) and iridium(iii) complexes: Tridentate N^C^N-cyclometallating ligands lead to high luminescence efficiencies

机译：发出亮橙色/红色的铑（iii）和铱（iii）配合物：三齿N ^ C ^ N-环金属化配体导致高发光效率

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Rhodium(iii) complexes rarely display strong phosphorescence, in contrast to well-known iridium(iii) complexes with cyclometallating ligands. This study shows how 1,3-bis(1-isoquinolyl)benzene cyclometallates to Rh(iii) through N^C^N-coordination to give complexes with unprecedented phosphorescence quantum yields at room temperature. Their highly emissive Ir(iii) analogues are also described.

机译：与众所周知的具有环金属化配体的铱（iii）配合物相比，铑（iii）配合物很少显示出强烈的磷光。这项研究表明1,3-双（1-异喹啉基）苯环金属盐如何通过N ^ C ^ N配位生成Rh（iii），从而在室温下以前所未有的磷光量子产率产生配合物。还描述了其高发射率的Ir（iii）类似物。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第29期|共6页
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Gildea L.F.; Batsanov A.S.; Williams J.A.G.;
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Bright orange/red-emitting; Tridentate N^C^N-cyclometallating ligands lead; high luminescence efficiencies;

机译：发射橙色/红色的亮光;直链的N ^ C ^ N-环金属配体铅;高发光效率;

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1. Bright orange/red-emitting rhodium(iii) and iridium(iii) complexes: Tridentate N^C^N-cyclometallating ligands lead to high luminescence efficiencies [J] . Gildea L.F., Batsanov A.S., Williams J.A.G. Dalton transactions: An international journal of inorganic chemistry . 2013,第29期

机译：发出亮橙色/红色的铑（iii）和铱（iii）配合物：三齿N ^ C ^ N-环金属化配体导致高发光效率
2. ABSORPTION SPECTRA, LUMINESCENCE PROPERTIES, AND ELECTROCHEMICAL BEHAVIOR OF CYCLOMETALATED IRIDIUM(III) AND RHODIUM(III) COMPLEXES WITH A BIS(PYRIDYL)TRIAZOLE LIGAND [J] . Calogero G., Serroni S., Ricevuto V., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 1995,第3期

机译：双（吡啶基）三唑配体的环化铱和铑配合物的吸收光谱，发光性质和电化学行为
3. Mono and dinuclear iridium(iii) complexes featuring bis-tridentate coordination and Schiff-base bridging ligands: the beneficial effect of a second metal ion on luminescence [J] . Puttock Emma V, Sil Amit, Yufit Dmitry S., Dalton transactions: An international journal of inorganic chemistry . 2020,第30期

机译：单曲和二维铱（III）配合物，配合物，具有双三齿协调和席夫基础桥接配体：第二金属离子对发光的有益效果
4. Bifunctional Selective Hydrosilylation of Terminal Alkynes by Bis(carbene)Iridium(III)and Rhodium(III)Complexes [C] . Luis A.Oro Annual Saudi-Japan Symposium on Technology in Petroleum Refining and Petrochemicals . 2018

机译：双（卡宾烯）铱（III）和铑（III）配合物的末端炔烃的双官能选择性氢化硅烷化
5. I. Synthesis and reactivity of chiral iridium(III) and rhodium(III) complexes. II. Platinum-catalyzed iridium-methyl and iridium-phenyl bond formation [D] . Smith, Stuart Edward 2008

机译：I.手性铱（III）和铑（III）配合物的合成和反应性。二。铂催化的铱甲基和铱苯基键的形成
6. An Unprecedented Family of Luminescent Iridium(III)Complexes Bearing a Six-Membered Chelated Tridentate C^N^C Ligand [O] . Claus Hierlinger, Thierry Roisnel, David B. Cordes, -1

机译：前所未有的发光铱族（III）带有六元螯合三齿C ^ N ^ C配体的配合物
7. Mono and dinuclear iridium(iii) complexes featuring bis-tridentate coordination and Schiff-base bridging ligands: the beneficial effect of a second metal ion on luminescence [O] . Emma V. Puttock, Amit Sil, Dmitry S. Yufit, 2020

机译：单曲和二维铱（III）配合物，配合物，具有双三齿协调和席夫基础桥接配体：第二金属离子对发光的有益效果

Bright orange/red-emitting rhodium(iii) and iridium(iii) complexes: Tridentate N^C^N-cyclometallating ligands lead to high luminescence efficiencies

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