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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe_5CoMo_22As_2O _85(H_2O)]~(15-)
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Single-molecule magnet based on a C-type polyoxomolybdate with an S = 11 ground state: [Fe_5CoMo_22As_2O _85(H_2O)]~(15-)

机译:基于具有S = 11基态的C型聚钼钼酸盐的单分子磁体:[Fe_5CoMo_22As_2O _85(H_2O)]〜(15-)

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摘要

A C-type polyoxomolybdate containing a mixed-transition metal cluster Fe_5Co has been prepared as an ammonium salt, (NH_4) _(15)[Fe_5CoMo_(22)As_2O_(85)(H _2O)]·15H_2O (1). Interestingly, the magnetism measurements show that the compound exhibits not only an overall ferromagnetic cluster with a large spin ground state of S = 11 but also the behavior of single-molecule magnets.
机译:已经制备了包含混合过渡金属簇Fe_5Co的C型聚氧钼酸盐作为铵盐(NH_4)_(15)[Fe_5CoMo_(22)As_2O_(85)(H _2O)]·15H_2O(1)。有趣的是,磁性测量表明该化合物不仅表现出具有大的自旋基态S = 11的整体铁磁簇,而且还表现出单分子磁体的行为。

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