Mixed valence η~6-arene cobalt(i) and cobalt(ii) compound

Azhakar R.; Ghadwal R.S.; Roesky H.W.; Hey J.; Krause L.; Stalke D.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Mixed valence η~6-arene cobalt(i) and cobalt(ii) compound

【24h】

Mixed valence η~6-arene cobalt(i) and cobalt(ii) compound

机译：价化价η〜6-芳烃钴（i）和钴（ii）化合物

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相似文献
相关主题

摘要

The first carbonyl free mixed valence cobalt(i)/cobalt(ii) compound [2{L_2Co(i)(η~6-C_7H_8)}] ~(2+) [Co(ii)_2Cl_6]~(2-) (1) [L = PhC(N~tBu)_2SiCl] was obtained by the reaction of four equivalents of anhydrous CoCl_2 with five equivalents of N-heterocyclic chlorosilylene L. In contrast, the reaction of L with CoBr _2 yielded [L_2CoBr_2] (2). Compound 1 was formed by the cleavage of Co-Cl bonds, the reduction of Co(ii) to Co(i) and by the coordination of a toluene molecule. The chlorosilylene (L) functions as a reducing agent as well as a neutral σ-donor ligand. The toluene molecule coordinates to the Co(i) atom in an η~6-fashion.

机译：第一无羰基混合价钴（i）/钴（ii）化合物[2 {L_2Co（i）（η〜6-C_7H_8）}]〜（2+）[Co（ii）_2Cl_6]〜（2-）（ 1）[L = PhC（N〜tBu）_2SiCl]通过四当量的无水CoCl_2与五当量的N-杂环氯硅烷L的反应获得。相反，L与CoBr _2的反应生成了[L_2CoBr_2]（2 ）。通过裂解Co-Cl键，将Co（ii）还原成Co（i）以及通过甲苯分子的配位形成化合物1。氯亚甲硅烷基（L）充当还原剂以及中性σ供体配体。甲苯分子以η-6方式配位至Co（i）原子。

著录项

来源
《Dalton transactions: An international journal of inorganic chemistry》 |2013年第28期|共5页
作者
Azhakar R.; Ghadwal R.S.; Roesky H.W.; Hey J.; Krause L.; Stalke D.;
展开▼
作者单位

展开▼
收录信息
原文格式 PDF
正文语种 eng
中图分类
关键词
valence η~6-arene cobalt(i); cobalt(ii) compound; toluene molecule coordinates;

机译：价η〜6-芳烃钴（i）;钴（ii）化合物;甲苯分子坐标;

相似文献

外文文献
中文文献
专利

1. Mixed valence η~6-arene cobalt(i) and cobalt(ii) compound [J] . Azhakar R., Ghadwal R.S., Roesky H.W., Dalton transactions: An international journal of inorganic chemistry . 2013,第28期

机译：价化价η〜6-芳烃钴（i）和钴（ii）化合物
2. Magnetic Properties of End-to-End Azide-Bridged Tetranuclear Mixed-Valence Cobalt(III)/Cobalt(II) Complexes with Reduced Schiff Base Blocking Ligands and DFT Study [J] . Abhisek Banerjee, Snehasis Banerjee, Carlos J. Gómez García, ACS Omega . 2019,第24期

机译：席夫碱封闭配体减少的端到端叠氮桥联四价混合价钴（III）/钴（II）的磁性和DFT研究
3. Magnetic Properties of End-to-End Azide-Bridged Tetranuclear Mixed-Valence Cobalt(III)/Cobalt(II) Complexes with Reduced Schiff Base Blocking Ligands and DFT Study [J] . Abhisek Banerjee, Snehasis Banerjee, Carlos J. Gómez García, ACS Omega . 2019,第24期

机译：席夫碱封闭配体减少的端到端叠氮桥联四价混合价钴（III）/钴（II）的磁性和DFT研究
4. Anion-regulated Mixed-valency of Cobalt(II/III) Centers in Non-Coulombic Ionic Crystals [C] . Nobuto Yoshinari, Akari Hashimoto, Motohiro Nakano 日本化学会春季年会 . 2020

机译：非库仑离子晶体中钴（II / III）中心的阴离子混合级
5. Developing artificial proteases and nucleases: Catalytic hydrolysis of unactivated amides, nitriles and phosphates. Part~I. Hydrolysis of phosphate esters promoted by cobalt(III) complexes. Part~II. Hydration of nitriles catalyzed by cobalt(III) complexes. Part~III. Hydrolysis of amides promoted by cobalt(III) complexes. [D] . Kim, Jung Hee. 1992

机译：开发人造蛋白酶和核酸酶：催化水解未活化的酰胺，腈和磷酸盐。第一部分钴（III）配合物促进的磷酸酯的水解。第二部分钴（III）配合物催化的腈水合。第三部分钴（III）配合物促进的酰胺水解。
6. One-Pot Self-Assembly of Dinuclear Tetranuclear and H-Bonding-Directed Polynuclear Cobalt(II) Cobalt(III) and Mixed-Valence Co(II)/Co(III) Complexes of Schiff Base Ligands with Incomplete Double Cubane Core [O] . Santokh S. Tandon, Neil Patel, Scott D. Bunge, 2020

机译：二核四核和H键合的多核钴（II）钴（III）和混合价CO（II）/ CO（III）复合物的单核四核和H键合的多核钴（II）具有不完全的双副Cubane核
7. One-Pot Self-Assembly of Dinuclear, Tetranuclear, and H-Bonding-Directed Polynuclear Cobalt(II), Cobalt(III), and Mixed-Valence Co(II)/Co(III) Complexes of Schiff Base Ligands with Incomplete Double Cubane Core [O] . Santokh S. Tandon, Neil Patel, Scott D. Bunge, 2020

机译：二核，四核和H键合的多核钴（II），钴（III）和混合价CO（II）/ CO（III）复合物的单核，四核和H键合的多核钴（II），具有不完全的双副Cubane核
8. Spectrophotometric Determination of Cobalt(II) In the Presence of the Cobalt(III) Coordination Compound 2-(5-Cyanotetrazolato)Pentaamminecobalt(III) Perchlorate [R] . Merrill, R. M. 1980

机译：钴（III）配位化合物2-（5-氰基四唑）五氮杂钴（III）高氯酸盐存在下分光光度法测定钴（Ⅱ）

Mixed valence η~6-arene cobalt(i) and cobalt(ii) compound

摘要

著录项

相似文献

相关主题

期刊订阅