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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >A distorted honeycomb motif in divalent transition metal compounds based on 4-phosphonbenzoic acid and exchange coupled Co(ii) and Cu(ii): Synthesis, structural description and magnetic properties
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A distorted honeycomb motif in divalent transition metal compounds based on 4-phosphonbenzoic acid and exchange coupled Co(ii) and Cu(ii): Synthesis, structural description and magnetic properties

机译:基于4-膦基苯甲酸并交换耦合的Co(ii)和Cu(ii)的二价过渡金属化合物中的扭曲蜂窝状图案:合成,结构描述和磁性

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摘要

The first example of a two-dimensional inorganic hybrid material with cobalt as an open-shell transition metal ion and 4-phosphonbenzoic acid as a linker is presented together with its copper analogue. For both metal ions the inorganic part consists of edge-sharing metal-oxygen octahedra leading to a metal honeycomb motif. The magnetic properties of the cobalt compound are reported together with those of the corresponding copper compound based on the remarkably six-coordinated copper(ii) ions.
机译:提出了二维无机杂化材料的第一个例子,其中以钴为开壳过渡金属离子,并以4-膦苯甲酸为连接基及其铜类似物。对于这两种金属离子,无机部分均由边缘共享的金属氧八面体组成,从而形成金属蜂窝图案。基于显着六配位的铜(ii)离子,报告了钴化合物的磁性和相应的铜化合物的磁性。

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