β-Substituted ferrocenyl porphyrins: Synthesis, structure, and properties

Sharma R.; Gautam P.; Mobin S.M.; Misra R.

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β-Substituted ferrocenyl porphyrins: Synthesis, structure, and properties

机译：β-取代的二茂铁基卟啉：合成，结构和性质

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β-Substituted ferrocenyl porphyrins were designed and synthesized by the Pd-catalyzed Sonogashira cross-coupling reaction. The UV-vis absorption, emission, and cyclic voltammetric results indicate strong electronic communication between ferrocene and porphyrin. The porphyrin 4a is non-emissive in nature, while 4b and 4c show reduced fluorescence quantum yield. The single crystal X-ray structure of 4b is reported, which shows extensive C-H-π interactions.

机译：通过Pd催化的Sonogashira交叉偶联反应设计并合成了β-取代的二茂铁基卟啉。紫外可见吸收，发射和循环伏安法结果表明二茂铁与卟啉之间具有很强的电子连通性。卟啉4a本质上是非发射性的，而4b和4c显示出降低的荧光量子产率。报告了4b的单晶X射线结构，显示出广泛的C-H-π相互作用。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第15期|共7页
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Sharma R.; Gautam P.; Mobin S.M.; Misra R.;
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β-Substituted ferrocenyl porphyrins: Synthesis, structure, and properties

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