Remarkable acidity independent actinide extraction with a both-side diglycolamide-functionalized calix[4]arene

Mohapatra P.K.; Sengupta A.; Iqbal M.; Huskens J.; Godbole S.V.; Verboom W.

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Remarkable acidity independent actinide extraction with a both-side diglycolamide-functionalized calix[4]arene

机译：双面二甘醇酰胺官能化的杯[4]芳烃萃取具有显着的酸度独立性的act系元素

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A novel solvent system containing a newly synthesized both-side diglycolamide-functionalized calix[4]arene (L-I) in a room temperature ionic liquid showed highly efficient extraction of actinides and a remarkable acid concentration independent extraction of trivalent actinide ion, Am3+ suggesting its possible use for high level radioactive waste remediation. The nature of the complexes was ascertained by slope analysis, luminescence spectroscopic investigations and from the thermodynamic parameters. The sustainability of the solvent system for long term applications was also investigated.

机译：在室温离子液体中包含新合成的双侧双甘醇酰胺官能化的杯[4]亚芳基（LI）的新型溶剂系统显示出高效的of系元素萃取和显着的酸浓度独立性的三价act系离子Am3 +萃取，表明其可能用于高水平放射性废物的修复。配合物的性质通过斜率分析，发光光谱研究和热力学参数确定。还研究了溶剂系统在长期应用中的可持续性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第24期|共5页
作者
Mohapatra P.K.; Sengupta A.; Iqbal M.; Huskens J.; Godbole S.V.; Verboom W.;
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正文语种 eng
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关键词
acidity; actinide; system;

机译：酸度;act系;体系;

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1. Remarkable acidity independent actinide extraction with a both-side diglycolamide-functionalized calix[4]arene [J] . Mohapatra P.K., Sengupta A., Iqbal M., Dalton transactions: An international journal of inorganic chemistry . 2013,第24期

机译：双面二甘醇酰胺官能化的杯[4]芳烃萃取具有显着的酸度独立性的act系元素
2. Diglycolamide-functionalized calix[4]arenes showing unusual complexation of actinide ions in room temperature ionic liquids: Role of ligand structure, radiolytic stability, emission spectroscopy, and thermodynamic studies [J] . Mohapatra P.K., Sengupta A., Iqbal M., Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2013,第5期

机译：二甘醇酰胺官能化的杯芳烃[4]芳烃显示room离子在室温离子液体中的异常络合：配体结构，辐射稳定性，发射光谱和热力学研究的作用
3. Highly efficient uptake of neptunium from acidic feeds using two solid phase extraction resins containing diglycolamide-functionalized calix[4]arene ligands [J] . Gujar Rajesh B., Mohapatra Prasanta K., Iqbal Mudassir, Journal of chromatography, A: Including electrophoresis and other separation methods . 2021,第1期

机译：使用含有二氯胺胺官能化胶片[4]芳烃配体的两种固相提取树脂的酸性饲料高效吸收Neptunium
4. LANTHANIDE AND ACTINIDE EXTRACTION WITH CALIX4- AND CALIX6ARENES BEARING AMIDE GROUPS [C] . Nguyen TK Dunga, Kenji Kunogi, Rainer Ludwig International solvent extraction conference . 2001

机译：镧系元素和滑动素萃取4 - 和CALIX 6培养酰胺基团
5. Lower-rim chemistry of calix(5)arenes, isolation of calix(9--20)arenes, and investigations of the mechanisms of the base-induced and acid-catalyzed calixarene-forming reactions [D] . Stewart, Donald Ralph 1997

机译：杯芳烃（5）芳烃的下边缘化学，杯芳烃（9--20）芳烃的分离，以及碱诱导的和酸催化的杯芳烃形成反应机理的研究
6. Syntheses and structural studies of calix4arene–nucleoside and calix4arene–oligonucleotide hybrids [O] . Su Jeong Kim, Byeang Hyean Kim 2003

机译：杯4芳烃-核苷和杯4芳烃-寡核苷酸杂种的合成和结构研究
7. Electrochemical study of two tris-O-substituted calix[4]arenes: 25,27-dipropoxy-26-hydroxy-28-benzoyloxycalix[4]arene(partial cone) and 25,27-dibenzyl-26-hydroxy-28-benzoyloxy-calix[4]-arene (partial cone). Electro synthesis of the corresponding calix[4]arene-monoquinones [O] . Louati, Alain, Spraula, Julien, Gabelica, Valérie, 2006

机译：两种三-O-取代杯[4]芳烃的电化学研究：25,27-二丙氧基-26-羟基-28-苯甲酰氧基杯[4]芳烃（部分锥体）和25,27-二苄基-26-羟基-28-苯甲酰氧基-calix [4] -arene（部分锥体）。相应杯[4]芳烃-单醌的电合成

Remarkable acidity independent actinide extraction with a both-side diglycolamide-functionalized calix[4]arene

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