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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Self-assembly between dicarboxylate ions and binuclear europium complexes: Moving to water - PH dependence and effects of buffers
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Self-assembly between dicarboxylate ions and binuclear europium complexes: Moving to water - PH dependence and effects of buffers

机译:二羧酸根离子与双核euro络合物之间的自组装:迁移至水-PH依赖性和缓冲液的作用

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摘要

Binuclear lanthanide complexes consisting of two lanthanide binding domains in kinetically stable DO3A binding pockets linked by a 3-functionalized meta-xylyl bridge form stable 1:1 adducts with isophthalate and dinicotinate in water. The influence of buffer, pH and ligand structure on the binding of dinicotinate has been investigated.
机译:双核镧系元素络合物由动力学稳定的DO3A结合口袋中的两个镧系元素结合域组成,这些结合域通过3官能化的间二甲苯基桥连接在一起,在水中与间苯二甲酸和二烟酸酯形成稳定的1:1加合物。研究了缓冲液,pH和配体结构对二烟酸酯结合的影响。

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