Assembling 1D magnetic chain based on octacyanotungstate(v) and [Cu _2L_2Ln] sub-building units (Ln = Eu, Gd, Tb and Dy)

Song X.-J.; Zhang Z.-C.; Xu Y.-L.; Wang J.; Zhou H.-B.; Song Y.

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Assembling 1D magnetic chain based on octacyanotungstate(v) and [Cu _2L_2Ln] sub-building units (Ln = Eu, Gd, Tb and Dy)

机译：基于八环非钨酸盐（v）和[Cu _2L_2Ln]子结构单元（Ln = Eu，Gd，Tb和Dy）组装一维磁链

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Reaction of (NBu_3H)_3[W(CN)_8]·H _2O and linear trinuclear complexes [Cu~(II) _2L _2Ln~(III)(NO_3)_3] (L = 2,6-di(acetoacetyl)pyridine, Ln = Eu (1), Gd (2), Tb (3) and Dy (4)) leads to the formation of four one-dimensional (1D) complexes. Single crystal X-ray analysis reveals that [W(CN)_8]~(3-) bridges between the [Cu~(II) _2L_2Ln~(III)] sub-building units to construct the alternative chains. Magnetic investigation indicates that ferromagnetic interaction occurred between all paramagnetic ions and the slow magnetic relaxation properties were observed in complexes 3 and 4.

机译：（NBu_3H）_3 [W（CN）_8]·H _2O与线性三核配合物[Cu〜（II）_2L _2Ln〜（III）（NO_3）_3]（L = 2,6-二（乙酰乙酰基）吡啶， Ln = Eu（1），Gd（2），Tb（3）和Dy（4））导致形成四个一维（1D）配合物。单晶X射线分析表明，[W（CN）_8]〜（3-）在[Cu〜（II）_2L_2Ln〜（III）]子结构单元之间架桥以构建替代链。磁性研究表明，所有顺磁性离子之间都发生了铁磁相互作用，并且在配合物3和4中观察到了慢磁弛豫特性。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第26期|共8页
作者
Song X.-J.; Zhang Z.-C.; Xu Y.-L.; Wang J.; Zhou H.-B.; Song Y.;
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正文语种 eng
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chain; sub-building; units;

机译：链;子建筑;单元;

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1. Assembling 1D magnetic chain based on octacyanotungstate(v) and [Cu _2L_2Ln] sub-building units (Ln = Eu, Gd, Tb and Dy) [J] . Song X.-J., Zhang Z.-C., Xu Y.-L., Dalton transactions: An international journal of inorganic chemistry . 2013,第26期

机译：基于八环非钨酸盐（v）和[Cu _2L_2Ln]子结构单元（Ln = Eu，Gd，Tb和Dy）组装一维磁链
2. [(Cu-Radical)(2)-Ln]: Structure and Magnetic Properties of a Hetero-tri-spin Chain of Rings (Ln = Y-III, Gd-III, Tb-III, Dy-III) [J] . Wang Xiufeng, Hu Peng, Li Licun, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2015,第19期

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3. Ln~(III)Cu~(III)Schiff base compounds (Ln = Ce, Gd, Tb, Dy, Ho, Er): structural and magnetic properties [J] . Myrtil L.Kahn, T.M.Rajendiran, Yves Jeannin, Comptes Rendus Chimie . 2000,第2期

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Assembling 1D magnetic chain based on octacyanotungstate(v) and [Cu _2L_2Ln] sub-building units (Ln = Eu, Gd, Tb and Dy)

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