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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Selective CO_2 adsorption and proton conductivity in the two-dimensional Zn(ii) framework with protruded water molecules and flexible ether linkers
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Selective CO_2 adsorption and proton conductivity in the two-dimensional Zn(ii) framework with protruded water molecules and flexible ether linkers

机译:具有突出的水分子和柔性醚键的二维Zn(ii)骨架中的选择性CO_2吸附和质子传导性

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摘要

A two-dimensional (2D) Zn(ii) metal-organic framework with flexible aryl ether linkers and water molecules exposed to the pores was prepared. The supramolecular three-dimensional (3D) network is generated by the presence of extensive π-π contacts, which could be responsible for gas uptake. The water molecules and oxygen atoms from the flexible linkers create a polar environment within the integrated framework, leading to simultaneous selective CO_2 adsorption and proton conductivity in the two-dimensional Zn(ii) framework.
机译:制备了具有柔性芳基醚接头和暴露于孔中的水分子的二维(2D)Zn(ii)金属-有机骨架。超分子三维(3D)网络是由于存在大量的π-π接触而产生的,这可能是气体吸收的原因。来自柔性接头的水分子和氧原子在集成框架内创建一个极性环境,从而导致二维Zn(ii)框架中同时选择性吸附CO_2和质子传导性。

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