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首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Ternary self-assemblies in water: Forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)_3(dinicotinate)_2Cl
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Ternary self-assemblies in water: Forming a pentanuclear ReLn4 assembly by association of binuclear lanthanide binding pockets with fac-Re(CO)_3(dinicotinate)_2Cl

机译:水中的三元自组装:通过双核镧系元素结合口袋与fac-Re(CO)_3(dinicotinate)_2Cl的缔合形成五核ReLn4组装

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摘要

The self-assembly of higher order structures in water is realised by using the association of 1,3-biscarboxylates to binuclear meta-xylyl bridged DO3A complexes. Two dinicotinate binding sites are placed at a right-angle in a rhenium complex, which is shown to form a 1:2 complex with α, α′-bis(Eu·DO3A)-5-amino-m-xylene.
机译:通过使用1,3-双羧酸盐与双核间二甲苯基桥连的DO3A配合物的缔合,可​​以实现水中高级结构的自组装。两个二烟酸酯结合位点在a络合物中成直角放置,显示与α,α'-双(Eu·DO3A)-5-氨基-间二甲苯形成1:2络合物。

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