A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

Sch?ffer C.; Todea A.M.; B?gge H.; Floquet S.; Cadot E.; Korenev V.S.; Fedin V.P.; Gouzerh P.; Müller A.

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A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

机译：通过用硫化物配体代替骨架氧化物来调整金属硫属化物纳米胶囊性能的又一步

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Addition of [Mo_2 ~VO_2(μ-O)(μ-S)(aq)] ~(2+) linker-type units to a solution/dynamic library containing tungstates results via the formation of the complementary pentagonal {(W)W _5} units logically in the self-assembly of a mixed oxide/sulphide {W_(72)~(VI)Mo_(60)~V}-type Keplerate, thereby demonstrating the ability to tune the capsule's skeletal softness (the (μ-O)_2 and (μ-S)_2 scenarios are known) and providing options to influence differently important capsule-substrate interactions.

机译：[Mo_2〜VO_2（μ-O）（μ-S）（aq）]〜（2+）接头型单元向包含钨酸盐的溶液/动力学库中的添加是通过形成互补的五边形{{W} W _5}单元在氧化物/硫化物{W_（72）〜（VI）Mo_（60）〜V}型Keplerate的自组装中具有逻辑上的自组装性，从而证明了调节胶囊骨骼柔软度的能力（ O）_2和（μ-S）_2情况是已知的），并提供了影响不同重要胶囊与底物相互作用的选项。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第2期|共4页
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Sch?ffer C.; Todea A.M.; B?gge H.; Floquet S.; Cadot E.; Korenev V.S.; Fedin V.P.; Gouzerh P.; Müller A.;
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1. A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands [J] . Sch?ffer C., Todea A.M., B?gge H., Dalton transactions: An international journal of inorganic chemistry . 2013,第2期

机译：通过用硫化物配体代替骨架氧化物来调整金属硫属化物纳米胶囊性能的又一步
2. One-step synthesis of nickel cobalt sulphides particles: tuning the composition for high performance supercapacitors [J] . Zhang Huaihao, Guan Bing, Gu Jiangna, RSC Advances . 2016,第64期

机译：镍钴硫化物颗粒的一步合成：调整高性能超级电容器的组合物
3. One-step synthesis of nickel cobalt sulphides particles: tuning the composition for high performance supercapacitors [J] . Huaihao Zhang, Bing Guan, Jiangna Gu, RSC Advances . 2016,第64期

机译：镍钴硫化物颗粒的一步合成：调整高性能超级电容器的组合物
4. A two-step method synthesis and microwave absorption properties of double-shell Ni@/BN@BaTiO_3 nanocapsules [C] . Gui-Mei Shi, Yingzhu International Conference on Renewable Energy and Environmental Technology . 2014

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5. Tuning the properties of metal-ligand complexes to modify properties of supramolecular materials. [D] . Henderson, Ian M. 2012

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7. Real-time and stepwise deoxidization processes to tune the photoluminescence properties of graphene oxide using EC-SPR spectroscopy [O] . Nan-Fu Chiu, Cheng-Du Yang 2018

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A further step towards tuning the properties of metal-chalcogenide nanocapsules by replacing skeletal oxide by sulphide ligands

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