Position-selective intramolecular aromatic C-H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes

Ogata K.; Inomata S.; Fukuzawa S.-I.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Position-selective intramolecular aromatic C-H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes

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Position-selective intramolecular aromatic C-H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes

机译：（对-异丙基）钌（ii）配合物中的1,2,3-三唑-5-亚烷基（tzNHC）配体的位置选择性分子内芳族C-H键活化

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A series of 1,2,3-triazol-5-ylidene (tzNHC) complexes of a (p-cymene)ruthenium system was synthesized. The reactivity of the N-bonded and C-bonded aryl groups in the tzNHC ligand was found to be significantly different with respect to intramolecular aromatic C-H bond activation.

机译：合成了一系列（对-异丙基）钌系统的1,2,3-三唑-5-亚烷基（tzNHC）配合物。发现关于分子内芳族C-H键活化，tzNHC配体中N-键和C-键芳基的反应性显着不同。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第7期|共4页
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Ogata K.; Inomata S.; Fukuzawa S.-I.;
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1. Position-selective intramolecular aromatic C-H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes [J] . Ogata K., Inomata S., Fukuzawa S.-I. Dalton transactions: An international journal of inorganic chemistry . 2013,第7期

机译：（对-异丙基）钌（ii）配合物中的1,2,3-三唑-5-亚烷基（tzNHC）配体的位置选择性分子内芳族C-H键活化
2. Autocatalytic intermolecular versus intramolecular deprotonation in C-H bond activation of functionalized arenes by ruthenium(II) or palladium(II) complexes [J] . Fabre I., Von Wolff N., Le Duc G., Chemistry: A European journal . 2013,第23期

机译：钌（II）或钯（II）配合物在官能化芳烃的C-H键活化中的自催化分子间去质子与分子内去质子化
3. Highly Selective Intramolecular Carbene Insertion into Primary C-H Bond of α-Diazoacetamides Mediated by a (p-Cymene)ruthenium(II)Carboxylate Complex [J] . Vanessa Kar-Yan Lo, Zhen Guo, Matthew Kwok-Wai Choi, Journal of the American Chemical Society . 2012,第18期

机译：（p-Cymene）钌（II）羧酸盐配合物介导的α-重氮乙酰胺的高选择性分子内碳氢键插入伯C-H键
4. A Ruthenium-Catalyzed Reaction of Aromatic Ketones with Organoboronic Acid Esters:A New Method for C-C Bond Formation via C-H Bonds Cleavage [C] . Fumitoshi Kakiuchi, Shintaro Kan, Kimitaka Igi, Symposium on Organometallic Chemistry . 2003

机译：芳香酮与有机硼酸酯的芳香酮催化反应：通过C-H键切割的C-C键形成新方法
5. Synthesis and Characterization of Group VIII & IX Transition Metal Complexes and Their Application in C-H Bond Activation and Hydrogen Transformation [D] . Yuan, Hongmei. 2018

机译：VIII和IX过渡金属配合物组的合成与表征及其在C-H键活化和氢转化中的应用
6. Intramolecular C-N Bond Formation via Thermal Arene C-H Bond Activation Supported by Au(III) Complexes [O] . Julianna Mruk, Agata J. Pacuła-Miszewska, Leszek Pazderski, 2021

机译：通过Au（III）配合物支持的热芳烃C-H键活化的分子内C-N键形成
7. Combined Experimental and Computational Studies on the Nature of Aromatic C-H Activation by Octahedral Ruthenium(II) Complexes: Evidence for σ-Bond Metathesis from Hammett Studies [O] . DeYonker, Nathan J., Foley, Nicholas A., Cundari, Thomas R., 1964-, 2007

机译：八面体钌（II）配合物对芳香族C-H活化性质的联合实验和计算研究：Hammett研究中σ-键复分解的证据

Position-selective intramolecular aromatic C-H bond activation of 1,2,3-triazol-5-ylidene (tzNHC) ligands in (p-cymene)ruthenium(ii) complexes

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