Selective synthesis of cis- and trans-[(NHC~(Me))_2-PtCl_2] and [NHC~(Me)Pt(cod)Cl][NHC~(Me)PtCl_3] using NHC~(Me)SiCl_4

Lesley C. Lewis-Alleyne; Bassem S. Bassil; Tobias B?ttcher; Gerd-Volker R?schenthaler

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Selective synthesis of cis- and trans-[(NHC~(Me))_2-PtCl_2] and [NHC~(Me)Pt(cod)Cl][NHC~(Me)PtCl_3] using NHC~(Me)SiCl_4

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Selective synthesis of cis- and trans-[(NHC~(Me))_2-PtCl_2] and [NHC~(Me)Pt(cod)Cl][NHC~(Me)PtCl_3] using NHC~(Me)SiCl_4

机译：使用NHC〜（Me）SiCl_4选择性合成顺式和反式[（NHC〜（Me））_ 2-PtCl_2]和[NHC〜（Me）Pt（cod）Cl] [NHC〜（Me）PtCl_3]

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NHC~(Me)SiCl_4 (NHC~(Me) = 1,3-dimethylimidazolidin-2-ylidene) was used to synthesise novel NHC~(Me)–Pt(II) complexes. An atypical trans–cis isomerisation process was also achieved for [(NHC~(Me))_2PtCl_2], while the synthesis of the unique double-complex salt [(NHC~(Me))Pt(cod)Cl] [(NHC~(Me))PtCl_3] (cod = 1,5-cyclooctadiene) revealed the first-ever N-heterocyclic carbene analogue of the Cossa’s salt anion.

机译：NHC〜（Me）SiCl_4（NHC〜（Me）= 1,3-二甲基咪唑烷基-2-亚甲基）用于合成新型的NHC〜（Me）–Pt（II）配合物。 [（NHC〜（Me））_ 2PtCl_2]也实现了非典型的反式-顺式异构化过程，同时合成了独特的双络合物盐[[NHC〜（Me））Pt（cod）Cl] [[NHC〜（Me））PtCl_3]（鳕鱼= 1,5-环辛二烯）揭示了Cossa盐阴离子的第一个N-杂环卡宾类似物。

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来源
《Dalton transactions: An international journal of inorganic chemistry》 |2014年第42期|共4页
作者
Lesley C. Lewis-Alleyne; Bassem S. Bassil; Tobias B?ttcher; Gerd-Volker R?schenthaler;
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正文语种 eng
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Selective; synthesis; NHC~(Me)SiCl_4;

机译：选择性合成NHC〜（Me）SiCl_4;

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1. Selective synthesis of cis- and trans-[(NHC~(Me))_2-PtCl_2] and [NHC~(Me)Pt(cod)Cl][NHC~(Me)PtCl_3] using NHC~(Me)SiCl_4 [J] . Lesley C. Lewis-Alleyne, Bassem S. Bassil, Tobias B?ttcher, Dalton transactions: An international journal of inorganic chemistry . 2014,第42期

机译：使用NHC〜（Me）SiCl_4选择性合成顺式和反式[（NHC〜（Me））_ 2-PtCl_2]和[NHC〜（Me）Pt（cod）Cl] [NHC〜（Me）PtCl_3]
2. Synthesis of (NHC)Rh(cod)Cl and (NHC)RhCl(CO)_2 complexes – Translation of the Rh- into the Ir-scale for the electronic properties of NHC ligands [J] . Stefanie Wolf, Herbert Plenio Journal of Organometallic Chemistry . 2009,第9a10期

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8. Preparation of New Phosphoranes (C6H5)2P(O)NHC6F5 and C6H5P(O)(NHC6F5)2, 1,3-Bis(pentafluorophenyl)2,4-diphenyl-1,3,2,4-diazadiphosphetidine (C6H5PNC6F5)2, and 1,3-Bis (2-fluorophenyl) 2,4-diphenyl-2,4-dioxo-1,3,2,4-diazadiphosphetidine (C6H5P(O)NC6H4F)2 [R] . Alam, K., Scott, B., Kirchmeier, R. L., 1991

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Selective synthesis of cis- and trans-[(NHC~(Me))_2-PtCl_2] and [NHC~(Me)Pt(cod)Cl][NHC~(Me)PtCl_3] using NHC~(Me)SiCl_4

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