Highly dispersed palladium nanoparticles grafted onto nanocrystalline starch for the oxidation of alcohols using molecular oxygen as an oxidant

Verma S.; Tripathi D.; Gupta P.; Singh R.; Bahuguna G.M.; Shivakumar K L.N.; Chauhan R.K.; Saran S.; Jain S.L.

首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Highly dispersed palladium nanoparticles grafted onto nanocrystalline starch for the oxidation of alcohols using molecular oxygen as an oxidant

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Highly dispersed palladium nanoparticles grafted onto nanocrystalline starch for the oxidation of alcohols using molecular oxygen as an oxidant

机译：接枝到纳米晶淀粉上的高度分散的钯纳米颗粒，用于使用分子氧作为氧化剂氧化醇

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Highly dispersed Pd-nanoparticles grafted onto amino-functionalized nanocrystalline starch were found to be excellent heterogeneous catalysts for the aerobic oxidation of a variety of alcohols to their corresponding carbonyl compounds in excellent yields. The prepared catalyst was found to be selective for the oxidation of primary alcohols to aldehydes without giving over-oxidation products and was recycled several times without any leaching of the metal into the solution.

机译：已发现接枝到氨基官能化的纳米晶淀粉上的高度分散的Pd纳米颗粒是出色的非均相催化剂，可将多种醇类有氧氧化成其相应的羰基化合物，且产率高。发现制得的催化剂对于伯醇氧化为醛具有选择性，而不会产生过氧化产物，并且可以循环使用几次，而不会将金属浸出到溶液中。

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《Dalton transactions: An international journal of inorganic chemistry》 |2013年第32期|共6页
作者
Verma S.; Tripathi D.; Gupta P.; Singh R.; Bahuguna G.M.; Shivakumar K L.N.; Chauhan R.K.; Saran S.; Jain S.L.;
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正文语种 eng
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Highly dispersed; palladium nanoparticles; molecular oxygen;

机译：高度分散;钯纳米粒子;分子氧;

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1. Highly dispersed palladium nanoparticles grafted onto nanocrystalline starch for the oxidation of alcohols using molecular oxygen as an oxidant [J] . Verma S., Tripathi D., Gupta P., Dalton transactions: An international journal of inorganic chemistry . 2013,第32期

机译：接枝到纳米晶淀粉上的高度分散的钯纳米颗粒，用于使用分子氧作为氧化剂氧化醇
2. Selective imine formation from alcohols and amines catalyzed by polymer incarcerated gold/palladium alloy nanoparticles with molecular oxygen as an oxidant [J] . Jean-Francois Soule, Hiroyuki Miyamura, Shu Kobayashi Chemical Communications . 2013,第4期

机译：聚合物嵌顿的金/钯合金纳米粒子以分子氧为氧化剂催化从醇和胺选择性形成亚胺
3. Highly dispersed iron oxides on mesoporous carbon for selective oxidation of benzyl alcohol with molecular oxygen [J] . Longlong Geng, Xiuyan Zhang, Wenxiang Zhang, Chemical Communications . 2014,第22期

机译：介孔碳上高度分散的氧化铁，用于用分子氧选择性氧化苄醇
4. Highly Dispersed Group IV, V Transition Metal Oxide Catalysts from Grafted Metallocalixarenes for Alkene Epoxidation [C] . Nicholas E. Thornburg, Justin M. Notestein AIChE Annual Meeting . 2014

机译：高度分散的第IV族，V过渡金属氧化物催化剂来自接枝金属丙烯酸烷烃，用于烯烃环氧化
5. Dynamics of carbon monoxide oxidation on palladium and platinum: A state-specific study of the translational excitation of carbon dioxide produced from carbon monoxide oxidation by adsorbed oxygen atoms on palladium and a comparison of carbon monoxide oxidation by adsorbed oxygen atoms and by nascent oxygen atoms on palladium and platinum. [D] . Wei, Cong. 1995

机译：一氧化碳在钯和铂上氧化的动力学：特定状态的研究，研究了钯吸附的氧原子转化为一氧化碳所产生的二氧化碳的平移激发，并比较了吸附的氧原子和新生氧原子对一氧化碳的氧化作用钯和铂。
6. Palladium(II) Catalyzed Cyclization-Carbonylation-Cyclization Coupling Reaction of (ortho-Alkynyl Phenyl) (Methoxymethyl) Sulfides Using Molecular Oxygen as the Terminal Oxidant [O] . Rong Shen, Taichi Kusakabe, Tomofumi Yatsu, 2016

机译：钯（II）分子氧作为末端氧化剂催化（邻炔基苯基）（甲氧基甲基）硫化物的环化-羰基化-环化偶联反应
7. Hydroxyapatite-Supported Palladium Nanoclusters: A Highly Active Heterogeneous Catalyst for Selective Oxidation of Alcohols by Molecular Oxygen [O] . -1

机译：羟基磷灰石负载的钯纳米能器：通过分子氧的选择性氧化醇的高活性异质催化剂

Highly dispersed palladium nanoparticles grafted onto nanocrystalline starch for the oxidation of alcohols using molecular oxygen as an oxidant

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