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Storylines in intercalation chemistry

机译:插层化学的故事情节

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摘要

Intercalation chemistry will soon be a hundred years old. The period of greatest activity in this field of solid state chemistry and physics was from about 1970 to 1990. The intercalation reactions are defined as topotactic solid state reactions and the products – the intercalation compounds – are clearly distinguished from inclusion and interstitial compounds. After a short historical introduction emphasizing the pioneering work of Ulrich Hofmann, the central topics and concepts will be reviewed and commented on. The most important ones, in my view, are: dichalcogenide intercalation compounds, the electrochemical intercalation and the search for new battery electrodes, the physics of graphite intercalation compounds, and the staging and interstratification phenomena. The relation to other fields of actual research and the demands for forthcoming research will also be addressed.
机译:插层化学很快就会有一百年历史了。在固态化学和物理学领域中,最活跃的时期是大约1970年至1990年。插层反应定义为全固态固态反应,并且明显地区分了产物(插层化合物)与夹杂和间隙化合物。在简短的历史介绍中强调了Ulrich Hofmann的开拓性工作之后,将对中心主题和概念进行评论。在我看来,最重要的是:二硫化氢插层化合物,电化学插层和寻找新的电池电极,石墨插层化合物的物理性质以及分段和层间化现象。与实际研究的其他领域的关系以及对即将进行的研究的需求也将得到解决。

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