Emissive molecular nanomagnets: introducing optical properties in triangular oximato {Mn_3 ~(III)} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues

Dimitris I. Alexandropoulos; Andrew M. Mowson; Melanie Pilkington; Vlasoula Bekiari; George Christou; Theocharis C. Stamatatos

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Emissive molecular nanomagnets: introducing optical properties in triangular oximato {Mn_3 ~(III)} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues

机译：发射性分子纳米磁铁：通过用其类似物故意取代简单的羧酸盐配体，从而在三角氧化硅{Mn_3〜（III）} SMM中引入光学性质

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The targeted replacement of acetate groups in the optically inactive [Mn_3 ~(III) O(O_2CMe)_3(mpko)_3](ClO_4) single-molecule magnet with their naphthalene, anthracene, and pyrene fluorescent analogues has led to three new emissive SMMs with enhanced photoluminescence properties and potential applications in the field of molecular electronics.

机译：光学惰性[Mn_3〜（III）O（O_2CMe）_3（mpko）_3]（ClO_4）单分子磁体中乙酸盐的目标取代为其萘，蒽和pyr荧光类似物，导致产生了三个新的自发光SMM具有增强的光致发光特性，并在分子电子学领域具有潜在的应用。

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《Dalton transactions: An international journal of inorganic chemistry》 |2014年第5期|共5页
作者
Dimitris I. Alexandropoulos; Andrew M. Mowson; Melanie Pilkington; Vlasoula Bekiari; George Christou; Theocharis C. Stamatatos;
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正文语种 eng
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Emissive molecular; introducing; ligands;

机译：发射分子;引入;配体;

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外文文献

1. Emissive molecular nanomagnets: introducing optical properties in triangular oximato {Mn_3 ~(III)} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues [J] . Dimitris I. Alexandropoulos, Andrew M. Mowson, Melanie Pilkington, Dalton transactions: An international journal of inorganic chemistry . 2014,第5期

机译：发射性分子纳米磁铁：通过用其类似物故意取代简单的羧酸盐配体，从而在三角氧化硅{Mn_3〜（III）} SMM中引入光学性质
2. Bifunctional Zn~(II)Ln~(III) Dinuclear Complexes Combining Field Induced SMM Behavior and Luminescence: Enhanced NIR Lanthanide Emission by 9?Anthracene Carboxylate Bridging Ligands [J] . María A. Palacios, Silvia Titos-Padilla, Jose? Ruiz, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2014,第3期

机译：场致SMM行为和发光相结合的双功能Zn〜（II）Ln〜（III）双核配合物：9？蒽羧酸桥联配体增强了近红外镧系元素的发射
3. Tetranuclear homo- (Zn~(II)_4 and Cd~(II)_4) and hetero-metal (Zn~(II)_2Tb~(III)_2 and Cd~(II)_2Tb~(III)_2) complexes with a pair of carboxylate ligands in a rare η~2: η~2:μ~4-bridging mode: Syntheses, structures and emission properties [J] . Abtab S.M.T., Audhya A., Kundu N., Dalton transactions: An international journal of inorganic chemistry . 2013,第5期

机译：四核同质（Zn〜（II）_4和Cd〜（II）_4）和杂金属（Zn〜（II）_2Tb〜（III）_2和Cd〜（II）_2Tb〜（III）_2）配合物稀少的η〜2：η〜2：μ〜4-桥联模式下的一对羧酸盐配体：合成，结构和发射性质
4. Bifunctional Zn(II)Ln(III) Dinuclear Complexes Combining Field Induced SMM Behavior and Luminescence: Enhanced NIR Lanthanide Emission by 9-Anthracene Carboxylate Bridging Ligands [O] . Palacios, Maria A., Titos-Padilla, Silvia, Ruiz, Jose, 2014

机译：结合场诱导smm行为和发光的双功能Zn（II）Ln（III）双核配合物：9-蒽羧酸桥联配体增强的近红外光谱发射

Emissive molecular nanomagnets: introducing optical properties in triangular oximato {Mn_3 ~(III)} SMMs from the deliberate replacement of simple carboxylate ligands with their fluorescent analogues

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