Nitrite complexes of the rare earth elements?

Jacky Pouessel; Pierre Thuéry; Jean-Claude Berthet; Thibault Cantat

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Nitrite complexes of the rare earth elements?

机译：稀土元素的亚硝酸盐络合物？

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The coordination chemistry of the nitrite anion has been investigated with rare earth elements, and the resulting complexes were structurally characterized. Among them, the first homoleptic examples of nitrite complexes of samarium, ytterbium and yttrium are described. The coordination behavior of the nitrite ion is directly controlled by the ionic radius of the metal cation. While the nitrito ligand is stable in the coordination sphere of cerium(III), it is readily reduced by SmI_2

机译：用稀土元素研究了亚硝酸根阴离子的配位化学，并对所得配合物进行了结构表征。其中，描述了sa，和钇的亚硝酸盐络合物的第一均质实例。亚硝酸根离子的配位行为直接受金属阳离子的离子半径控制。亚硝酸盐配体在铈（III）的配位域中稳定，但很容易被SmI_2还原

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《Dalton transactions: An international journal of inorganic chemistry》 |2014年第11期|共11页
作者
Jacky Pouessel; Pierre Thuéry; Jean-Claude Berthet; Thibault Cantat;
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正文语种 eng
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coordination; readily; reduced;

机译：协调;迅速;减少;

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1. Nitrite complexes of the rare earth elements? [J] . Jacky Pouessel, Pierre Thuéry, Jean-Claude Berthet, Dalton transactions: An international journal of inorganic chemistry . 2014,第11期

机译：稀土元素的亚硝酸盐络合物？
2. Zircon Alteration as a Proxy for Rare Earth Element Mineralization Processes in Carbonatite-Nordmarkite Complexes of the Mianning-Dechang Rare Earth Element Belt, China [J] . Liu Yan, Hou Zengqian, Zhang Rongqing, Economic geology and the bulletin of the Society of Economic Geologists . 2019,第4期

机译：锆石改变作为钢铁稀土元素腰带碳甲板 - 诺尔马德群系中稀土元素矿化过程的代理
3. Phosphoraneiminato complexes of rare earths elements. Syntheses and crystal structures of [M-2(C5H5)(3)(NPPh3)(3)]center dot 3C(7)H(8) with M = Y, Dy, and Er. Magnetic properties of [Dy-2(C5H5)(3)(NPPh3)(3)]center dot 3C(7)H(8) [German] [J] . Anfang S., Weller F., Borgmeier O., Zeitschrift fur Anorganische und Allgemeine Chemie . 1998,第1期

机译：稀土元素的磷杂亚胺络合物。 [M-2（C5H5）（3）（NPPh3）（3）]中心点3C（7）H（8）的合成和晶体结构，M = Y，Dy和Er。 [Dy-2（C5H5）（3）（NPPh3）（3）]中心点3C（7）H（8）的磁性
4. RARE EARTH ELEMENT COMPLEXES AS A LIQUID PRECURSOR FOR (RE)Ba_2Cu_3O_y THIN FILM BY MOCVD [C] . S. Yoshizawa, Y. Tasaki, K. Koyama, Advances in Cryogenic Engineering Materials . 2000

机译：稀土元素络合物作为MOCVD制备（RE）Ba_2Cu_3O_y薄膜的液体前驱体
5. Energy transfer pathways for nitrite-rare gas complexes in helium nanodroplets. [D] . Zadorozhnyy, Anton. 2009

机译：氦纳米液滴中亚硝酸盐稀有气体络合物的能量转移途径。
6. Accomplishing simple solubility-based separations of rare earth elements with complexes bearing size-sensitive molecular apertures [O] . Justin A. Bogart, Bren E. Cole, Michael A. Boreen, 2016

机译：通过具有大小敏感分子孔径的配合物完成稀土元素的简单基于溶解度的分离
7. Nitrite complexes of the rare earth elements [O] . Pouessel, Jacky, Thuéry, Pierre, Berthet, Jean-Claude, 2014

机译：稀土元素的亚硝酸盐络合物
8. Determination of Trace Amounts of Rare Earth Elements in Rare Earth Matrix by Graphite-Furnace Atomic Absorption Spectrometry [R] . Dantas, E. S. K. , Atalla, L. T. 1988

机译：石墨炉原子吸收光谱法测定稀土基体中痕量稀土元素

Nitrite complexes of the rare earth elements?

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