A tetradentate metalloligand: synthesis and coordination behaviour of a 2-pyridyl-substituted cyclobutadiene iron complex?

Babak Rezaei Rad; Dirk Herrmann; Christophe Lescop; Robert Wolf

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A tetradentate metalloligand: synthesis and coordination behaviour of a 2-pyridyl-substituted cyclobutadiene iron complex?

机译：四齿金属配体：2-吡啶基取代的环丁二烯铁配合物的合成和配位行为？

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The salt [K([18]crown-6){Cp*Fe(η~4-C_4py_4)}] (K1, py = 2-pyridyl, Cp* = C_5Me_5) is accessible by the reaction of an iron(0) naphthalene precursor and bis(2-pyridyl)acetylene. Cyclic voltammetry and preparative investigations demonstrate the electron-rich nature of K1, which is reversibly oxidized to neutral [Cp*Fe(η~4-C_4py_4)] (1) at a low potential. The first coordination studies with iron(II) and zinc(II) chloride show that all four 2-pyridyl units may be employed for metal coordination.

机译：盐[K（[18] cro-6）{Cp * Fe（η〜4-C_4py_4）}]（K1，py = 2-吡啶基，Cp * = C_5Me_5）可通过铁（0）的反应获得萘前体和双（2-吡啶基）乙炔。循环伏安法和制备研究表明，K1的富电子性质在低电势下可逆地氧化成中性[Cp * Fe（η〜4-C_4py_4）]（1）。与氯化铁（II）和氯化锌（II）的首次配位研究表明，所有四个2-吡啶基单元均可用于金属配位。

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《Dalton transactions: An international journal of inorganic chemistry》 |2014年第11期|共4页
作者
Babak Rezaei Rad; Dirk Herrmann; Christophe Lescop; Robert Wolf;
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正文语种 eng
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metal; coordination; units;

机译：金属;配位;单元;

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1. A tetradentate metalloligand: synthesis and coordination behaviour of a 2-pyridyl-substituted cyclobutadiene iron complex? [J] . Babak Rezaei Rad, Dirk Herrmann, Christophe Lescop, Dalton transactions: An international journal of inorganic chemistry . 2014,第11期

机译：四齿金属配体：2-吡啶基取代的环丁二烯铁配合物的合成和配位行为？
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8. Synthesis and characterization of new iron coordination complexes utilizing an asymmetric coordinating chelate ligand [R] . Watkins, B. E. , Satcher, J. H. 1995

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A tetradentate metalloligand: synthesis and coordination behaviour of a 2-pyridyl-substituted cyclobutadiene iron complex?

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