New cobalt, iron and chromium catalysts based on easy-to-handle N4-chelating ligands for the coupling reaction of epoxides with CO

M. Adolph; T. A. Zevaco; C. Altesleben; O. Walter; E. Dinjus

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New cobalt, iron and chromium catalysts based on easy-to-handle N4-chelating ligands for the coupling reaction of epoxides with CO

机译：基于易于处理的N4螯合配体的新型钴，铁和铬催化剂，用于环氧化物与CO的偶联反应

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In this contribution, we report the successful utilization of several transition metal complexes based on substituted N_4-N,N-bis(2-pyridinecarboxamide)-1,2-benzene chelating ligands as catalysts in the coup- ling of epoxides with carbon dioxide. The complexes were tested towards cyclohexene oxide and pro- pylene oxide. Additionally the recyclability of the catalytic system was evaluated and a broader catalytic screening involving several commercially available epoxides was carried out with selected catalysts.

机译：在这项贡献中，我们报道了基于取代的N_4-N，N-双（2-吡啶甲酰胺）-1,2-苯螯合配体的几种过渡金属络合物作为催化剂在环氧化物与二氧化碳偶联中的成功利用。测试了该配合物的环氧丙烷和环氧丙烷。此外，还评估了催化系统的可回收性，并使用选定的催化剂对涉及几种市售环氧化物的催化剂进行了更广泛的筛选。

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《Dalton transactions: An international journal of inorganic chemistry》 |2014年第8期|共12页
作者
M. Adolph; T. A. Zevaco; C. Altesleben; O. Walter; E. Dinjus;
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正文语种 eng
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iron; cobalt; epoxides;

机译：铁;钴;环氧化物;

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1. New cobalt, iron and chromium catalysts based on easy-to-handle N4-chelating ligands for the coupling reaction of epoxides with CO [J] . M. Adolph, T. A. Zevaco, C. Altesleben, Dalton transactions: An international journal of inorganic chemistry . 2014,第8期

机译：基于易于处理的N4螯合配体的新型钴，铁和铬催化剂，用于环氧化物与CO的偶联反应
2. Selective coupling of carbon dioxide and epoxystyrene via salicylaldimine-, thiophenaldimine-, and quinolinaldimine- iron(II), iron(III), chromium(III), and cobalt(III)/Lewis base catalysts [J] . Mahmoud Sunjuk, Adnan S. Abu-Surrah, Esraa Al-Ramahi Transition Metal Chemistry . 2013,第3期

机译：通过水杨醛亚胺，噻吩亚胺和喹啉亚胺-铁（II），铁（III），铬（III）和钴（III）/刘易斯碱催化剂对二氧化碳和环氧苯乙烯的选择性偶联
3. Trans- and cis- cobalt(III), iron(III), and chromium(III) complexes based on alpha- and gamma-diimine Schiff base ligands: Synthesis and evaluation of the complexes as catalysts for oxidation of L-cysteine [J] . Abu-Surrah AS, Abdel-Halim HM, Al-Qaisi FM Zeitschrift fur Anorganische und Allgemeine Chemie . 2008,第5期

机译：基于α-和γ-二亚胺席夫碱配体的反式和顺式钴（III），铁（III）和铬（III）配合物：配合物的合成和评价，作为L-半胱氨酸氧化的催化剂
4. GRAPHENE-BASED ELECTROCATALYSTS WITH ENHANCED PERFORMANCE TOWARDS OXYGEN REDUCTION REACTION DECORATED WITH COBALT,IRON AND/OR TITANIUM [C] . Giovanni Lemes, Jose Manuel Luque-Centeno, Elena Pastor World Conference on Carbon . 2020

机译：基于石墨烯的电催化剂，具有增强的氧气还原反应性能，装饰着钴，铁和/或钛
5. Pincer complexes of diamido-pyridine based ligand as catalysts for C-Cl and C-H bond activation for cross-coupling reactions. [D] . Gartia, Yashraj. 2013

机译：基于二酰胺基-吡啶基配体的钳形配合物，可作为C-Cl和C-H键活化的催化剂进行交叉偶联反应。
6. A Multi-Ligand Based Pd Catalyst for C–N Cross-Coupling Reactions [O] . Brett P. Fors, Stephen L. Buchwald -1

机译：的多基于配体的pd催化剂C-N交叉偶联反应
7. Iron-, Cobalt- and Chromium-catalyzed cross-coupling reactions of aromatics and heterocycles [O] . Kuzmina Olesya 2014

机译：铁，钴和铬催化芳烃和杂环的交叉偶联反应

New cobalt, iron and chromium catalysts based on easy-to-handle N4-chelating ligands for the coupling reaction of epoxides with CO

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