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Direct oxidative esterification of alcohols

机译:醇类的直接氧化酯化

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摘要

Esterification is a fundamental transformation in chemistry. Traditional esterification only largely occurs between carboxylic acid derivatives and alcohols, and often involves multistep processes. Developments in the transition-metal-catalysed and metal-free direct esterification of alcohols under oxidative conditions has opened a door to the efficient, sustainable and environmentally friendly synthesis of esters from readily available materials. This Perspective gives an overview which covers the recent development of this emerging field.
机译:酯化是化学的根本转变。传统的酯化仅主要发生在羧酸衍生物和醇之间,并且通常涉及多步过程。醇在氧化条件下的过渡金属催化和无金属直接酯化的进展为从容易获得的材料中高效,可持续和环保地合成酯打开了一扇门。本“观点”概述了该新兴领域的最新发展。

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